Advanced Catalysis Engineering

Integrating climate policies in the sustainability analysis of green chemicals
A. Nabera, A.J. Martín, R. Istrate, J. Pérez-Ramírez, G. Guillén-Gosálbez
Green Chem. 2024, in press (doi:10.1039/D4GC00392F, featured in the 25th Anniversary Collection)
Low-nuclearity CuZn ensembles on ZnZrO_x catalyze methanol synthesis from CO₂
T. Pinheiro Araújo, G. Giannakakis, J. Morales-Vidal, M. Agrachev, Z. Ruiz-Bernal, P. Preikschas, T. Zou, F. Krumeich, P.O. Willi, W.J. Stark, R.N. Grass, G. Jeschke, S. Mitchell, N. López, J. Pérez-Ramírez
Nat. Commun. 2024, in press (doi:10.1038/s41467-024-47447-6)
Droplet-based microfluidics reveals insights into cross‑coupling mechanisms over single‑atom heterogeneous catalysts
T. Moragues, G. Giannakakis, A. Ruiz-Ferrando, C.N. Borca, T. Huthwelker, A. Bugaev, A.J. deMello, J. Pérez-Ramírez, S. Mitchell
Angew. Chem. Int. Ed. 2024, in press (doi:10.1002/anie.202401056)
The future of chemical sciences is sustainable
S. Mitchell, A.J. Martín, G. Guillén-Gosálbez, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2024, in press (doi:10.1002/anie.202318676)
CO cofeeding affects product distribution in CH₃Cl coupling over ZSM-5 zeolite: pressure twists the plot
Z. Zhang, M. Vanni, X. Wu, P. Hemberger, A. Bodi, S. Mitchell, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2024, 63, e202401060 (doi:10.1002/anie.202401060)
Embracing data science in catalysis research
M. Suvarna, J. Pérez-Ramírez
Nat. Catal. 2024, in press (doi:10.1038/s41929-024-01150-3)
Active learning based guided synthesis of engineered biochar for CO₂ capture
X. Yuan, M. Suvarna, J.Y. Lim, J. Pérez-Ramírez, X. Wang, Y.S. Ok
Environ. Sci. Technol. 2024, 58, 6628−6636 (doi:10.1021/acs.est.3c10922, front cover)
Design of technical ZnO/ZrO₂ catalysts for CO₂ hydrogenation to green methanol
T. Zou, T. Pinheiro Araújo, M. Agrachev, X. Jin, F. Krumeich, G. Jeschke, S. Mitchell, J. Pérez-Ramírez
J. Catal. 2024, 430, 115344 (doi:10.1016/j.jcat.2024.115344, featured in the 60th Commemorative Anniversary Issue)
Consumer grade polyethylene recycling via hydrogenolysis on ultrafine supported ruthenium nanoparticles
S.D. Jaydev, A.J. Martín, M.E. Usteri, K. Chikri, H. Eliasson, R. Erni, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2024, 63, e202317526 (doi:10.1002/anie.202317526, back cover)
CO₂ electroreduction to syngas with tunable composition in an artificial leaf
F.L.P. Veenstra, T. Cibaka, A.J. Martín, D. Weigand, J. Kirchhoff, V. Smirnov, T. Merdzhanova, J. Pérez-Ramírez
ChemSusChem 2024, 17, e202400133 (doi:10.1002/cssc.202301398, front cover)
Quantitative description of metal center organization and interactions in single atom catalysts
K. Rossi, A. Ruiz-Ferrando, D. Faust Akl, V. Gimenez Abalos, J. Heras-Domingo, R. Graux, X. Hai, J. Lu, D. Garcia-Gasulla, N. López, J. Pérez-Ramírez, S. Mitchell
Adv. Mater. 2024, 36, 2307991 (doi:10.1002/adma.202307991, frontispiece)
Transcending scales in catalysis for sustainable development
S. Mitchell, A.J. Martín, J. Pérez-Ramírez
Nat. Chem. Eng. 2024, 1, 13-15 (doi:10.1038/s44286-023-00005-1)
Language models and protocol standardization guidelines for accelerating synthesis planning in heterogeneous catalysis
M. Suvarna, A.C. Vaucher, S. Mitchell, T. Laino, J. Pérez-Ramírez
Nat. Commun. 2023, 14, 7964 (doi:10.1038/s41467-023-43836-5)
Lattice-stabilized chromium atoms on ceria for N₂O synthesis
Q. Yang, I. Surin, J. Geiger, H. Eliasson, M. Agrachev, V.A. Kondratenko, A. Zanina, F. Krumeich, G. Jeschke, R. Erni, E.V. Kondratenko, N. Lopez, J. Pérez-Ramírez
ACS Catal. 2023, 13, 15977-15990 (doi:10.1021/acscatal.3c04463)
Reaction environment design for multigram synthesis via Sonogashira coupling over heterogeneous palladium single-atom catalysts
D. Poier, D. Faust Akl, E. Lucas, A. Rodrigues Machado, G. Giannakakis, S. Mitchell, G. Guillén-Gosálbez, R. Marti, J. Pérez-Ramírez
ACS Sustainable Chem. Eng. 2023, 11, 16935-16945 (doi:10.1021/acssuschemeng.3c04183)
Direct electroreduction of carbonate to formate
H. Ma, E. Ibáñez-Alé, R. Ganganahalli, J. Pérez-Ramírez, N. Lopez, B.S. Yeo
J. Am. Chem. Soc. 2023, 145, 24707-24716 (doi:10.1021/jacs.3c08079)
Evidence of bifunctionality of carbons and metal atoms in catalyzed acetylene hydrochlorination
V. Giulimondi, A. Ruiz-Ferrando, G. Giannakakis, I. Surin, M. Agrachev, G. Jeschke, F. Krumeich, N. López, A.H. Clark, J. Pérez-Ramírez
Nat. Commun. 2023, 14, 5557 (doi:10.1038/s41467-023-41344-0)
Geminal atom catalysis for cross-coupling
X. Hai, Y. Zheng, Q. Yu, N. Guo, S. Xi, X. Zhao, S. Mitchell, X. Luo, V. Tulus, M. Wang, X. Sheng, L. Ren, X. Long, J. Li, P. He, H. Lin, Y. Cui, X. Peng, J. Shi, J. Wu, C. Zhang, R. Zou, G. Guillén-Gosálbez, J. Pérez-Ramírez, M.J. Koh, Y. Zhu, J. Li, J. Lu
Nature 2023, 622, 754-760 (doi:10.1038/s41586-023-06529-z)
Economic and environmental competitiveness of ethane-based technologies for vinyl chloride synthesis
J.D. Medrano-García, V. Giulimondi, A. Ceruti, G. Zichittella, J. Pérez-Ramírez, G. Guillén-Gosálbez
ACS Sustainable Chem. Eng. 2023, 11, 13062-13069 (doi:doi:10.1021/acssuschemeng.3c03006)
Recent advances in heterogeneous single-cluster catalysis
X. Li, S. Mitchell, Y. Fang, J. Li, J. Pérez-Ramírez, J. Lu
Nat. Rev. Chem. 2023, 7, 754–767 (doi:10.1038/s41570-023-00540-8)
ZrO₂-promoted Cu-Co, Cu-Fe and Co-Fe catalysts for higher alcohol synthesis
Y. Ge, T. Zou, A.J. Martín, J. Pérez-Ramírez
ACS Catal. 2023, 13, 9946-9959 (doi:10.1021/acscatal.3c02534)
Reaction-induced metal-metal oxide interactions in Pd-In₂O₃/ZrO₂ catalysts drive selective and stable CO₂ hydrogenation to methanol
T. Pinheiro Araújo, J. Morales-Vidal, G. Giannakakis, C. Mondelli, H. Eliasson, R. Erni, J.A. Stewart, S. Mitchell, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2023, 62, e202306563 (doi:10.1002/anie.202306563, inside cover)
Angew. Chem. 2023, 42, e202310340 (doi:10.1002/ange.202306563)
NMR-based quantification of liquid products in CO₂ electroreduction on phosphate-derived nickel catalysts
P. Preikschas, A.J. Martín, B.S. Yeo, and J. Pérez-Ramírez
Commun. Chem. 2023, 6, 147 (doi:10.1038/s42004-023-00948-9)
Energy crisis in Europe enhances the sustainability of green chemicals
A. Nabera, I.R. Istrate, A.J. Martín, J. Pérez-Ramírez, G. Guillén-Gosálbez
Green Chem. 2023, 25, 6603-6611 (doi:10.1039/D3GC01053H, front cover)
Selective hydrogenolysis of 5-hydroxymethylfurfural to 5-methylfurfural over Au/TiO₂
L. Dong, J. Morales-Vidal, L. Mu, L. Li, N. López, J. Pérez-Ramírez, Z. Chen
Appl. Catal. B 2023, 335, 122893 (doi:10.1016/j.apcatb.2023.122893)
Selectivity control in palladium-catalyzed CH₂Br₂ hydrodebromination on carbon-based materials by nuclearity and support engineering
M. Vanni, V. Giulimondi, A. Ruiz-Ferrando, F. Krumeich, A. Clark, S. Mitchell, N. Lopez, J. Pérez-Ramírez
ACS Catal. 2023, 13, 5828-5840 (doi:10.1021/acscatal.2c06394)
Environmental and economic potential of decentralised electrocatalytic ammonia synthesis powered by solar energy
S.C. D’Angelo, A.J. Martín, S. Cobo, D. Freire Ordóñez, G. Guillén-Gosálbez, J. Pérez-Ramírez
Energy Environ. Sci. 2023, 16, 3314-3330 (doi:10.1039/D2EE02683J, inside front cover)
Reaction-induced formation of stable mononuclear Cu(I)Cl species on carbon for low-footprint vinyl chloride production
D. Faust Akl, G. Giannakakis, A. Ruiz-Ferrando, M. Agrachev, J.D. Medrano-García, G. Guillén-Gosálbez, G. Jeschke, A.H. Clark, O.V. Safonova, S. Mitchell, N. López, J. Pérez-Ramírez
Adv. Mater. 2023, 35, 2211464 (doi:10.1002/adma.202211464)
Absolute environmental sustainability assessment of renewable dimethyl ether fuelled heavy-duty trucks
M.A. Charalambous, V. Tulus, M.W. Ryberg, J. Pérez-Ramírez, G. Guillén-Gosálbez
Sustain. Energy Fuels 2023, 7, 1930-1941 (doi:10.1039/D2SE01409B)
Low‑valent manganese atoms stabilized on ceria for nitrous oxide synthesis
I. Surin, Z. Tang, J. Geiger, S. Damir, H. Eliasson, M. Agrachev, F. Krumeich, S. Mitchell, V.A. Kondratenko, E.V. Kondratenko, G. Jeschke, R. Erni, N. López, J. Pérez-Ramírez
Adv. Mater. 2023, 35, 2211260 (doi:10.1002/adma.202211260, back cover)
Identifying selective catalysts in polypropylene hydrogenolysis by decoupling scission pathways
S.D. Jaydev, M.E. Usteri, A.J. Martín, J.Pérez-Ramírez
Chem. Catal. 2023, 3, 100564 (doi:10.1016/j.checat.2023.100564, front cover)
An artificial leaf device built with earth-abundant materials for combined H₂ production and storage as formate with efficiency > 10%
C. Ampelli, D. Giusi, M. Miceli, T. Merdzhanov, V. Smirnov, U. Chime, O. Astakhov, A.J. Martín, F.L.P. Veenstra, F.A. Garcés Pineda, J. González-Cobos, M. García-Tecedor, S. Giménez, W. Jaegermann, G. Centi, J. Pérez-Ramírez, J.R. Galán-Mascarós, S. Perathoner
Energy Environ. Sci. 2023, 16, 1644-1661 (doi:10.1039/D2EE03215E)
Unraveling radical and oxygenate routes in the oxidative dehydrogenation of propane over boron nitride
Z. Zhang, J. Tian, X. Wu, I. Surin, J. Pérez-Ramírez, P. Hemberger, A. Bodi
J. Am. Chem. Soc. 2023, 145, 7910-7917 (doi:10.1021/jacs.2c12970, supplementary cover)
Challenges and opportunities in engineering the electronic structure of single-atom catalysts
V. Giulimondi, S. Mitchell, J. Pérez-Ramírez
ACS Catal. 2023, 13, 2981-2997 (doi:10.1021/acscatal.2c05992, supplementary cover)
Design of flame-made ZnZrO_x catalysts for sustainable methanol synthesis from CO₂
T. Pinheiro Araújo, J. Morales-Vidal, T. Zou, M. Agrachev, S. Verstraeten, P.O. Willi, R.N. Grass, G. Jeschke, S. Mitchell, N. López, J. Pérez-Ramírez
Adv. Energy Mater. 2023, 13, 2204122 (doi:10.1002/aenm.202204122, front cover)
Environmental sustainability assessment of hydrogen from waste polymers
C. Salah, S. Cobo, J. Pérez-Ramírez, G. Guillén-Gosálbez
ACS Sustainable Chem. Eng. 2023, 11, 3238-3247 (doi:10.1021/acssuschemeng.2c05729)
Chlorine-promoted copper catalysts for CO₂ electroreduction into highly reduced products
T. Zou, F.L.P. Veenstra, E. Ibáñez-Alé, R. García-Muelas, G. Zichittella, A.J. Martín, N. López, J. Pérez-Ramírez
Cell Rep. Phys. Sci. 2023, 4, 101294 (doi:10.1016/j.xcrp.2023.101294, front cover)
Tuning oxygen vacancies in Bi₄Ti₃O₁₂ nanosheets to boost piezo-photocatalytic activity
Q. Tang, J. Wu, X.-Z. Chen, R. Sanchis-Gual, A. Veciana, C. Franco, D. Kim, I. Surin, J. Pérez-Ramírez, A. Terzopoulou, N. Qin, M. Vukomanovic, B.J. Nelson, J. Puigmartí-Luis, S. Pané
Nano Energy 2023, 108, 108202 (doi:10.1016/j.nanoen.2023.108202)
Droplet-based microfluidics platform for the synthesis of single-atom heterogeneous catalysts
T. Moragues, S. Mitchell, D. Faust Akl, J. Pérez-Ramírez, A. deMello
Small Structures 2023, 4, 2200284 (doi:10.1002/sstr.202200284, front cover)
Trade-offs between sustainable development goals in carbon capture and utilisation
I. Ioannou, Á. Galán-Martín, J. Pérez-Ramírez, G. Guillén-Gosálbez
Energy Environ. Sci. 2023, 16, 113-124 (doi:10.1039/D2EE01153K, inside front cover, highlighted in Advanced Science News)
Identifying descriptors for promoted rhodium-based catalysts for higher alcohol synthesis via machine learning
M. Suvarna, P. Preikschas, J. Pérez-Ramírez
ACS Catal. 2022, 12, 15373-15385 (doi:10.1021/acscatal.2c04349)
Flame-made ternary Pd-In₂O₃-ZrO₂ catalyst with enhanced oxygen vacancy generation for CO₂ hydrogenation to methanol
T. Pinheiro Araújo, C. Mondelli, M. Agrachev, T. Zou, P.O. Willi, K.M. Engel, R.N. Grass, W.J. Stark, O.V. Safonova, G. Jeschke, S. Mitchell, J. Pérez-Ramírez
Nat. Commun. 2022, 13, 5610 (doi:10.1038/s41467-022-33391-w)
Photoionization reveals catalytic mechanisms
A. Bodi, P. Hemberger, J. Pérez-Ramírez
Nat. Catal. 2022, 5, 850-851 (doi:10.1038/s41929-022-00847-7)
Catalytic synergies in bimetallic Ru-Pt single atom catalysts via speciation control
V. Giulimondi, A. Ruiz-Ferrando, A.H. Clark, S.K. Kaiser, F. Krumeich, A.J. Martín, N. López, J. Pérez-Ramírez
Adv. Funct. Mater. 2022, 32, 2206513 (doi:10.1002/adfm.202206513)
Prospects of producing higher alcohols from carbon dioxide: a process system engineering perspective
C.H. Vo, J. Pérez-Ramírez, S. Farooq, I.A. Karimi
ACS Sustainable Chem. Eng. 2022, 10, 11875-11884 (doi:10.1021/acssuschemeng.2c02810)
Transfer hydrogenation with a carbon-nitride-supported palladium single-atom photocatalyst and water as a proton source
E. Zhao, M. Li, B. Xu, X. Wang, Y. Jing, D. Ma, S. Mitchell, J. Pérez-Ramírez, Z. Chen
Angew. Chem. Int. Ed. 2022, 61, e202207410 (doi:10.1002/anie.202207410)
Angew. Chem. 2022, 134, e202207410 (doi:10.1002/ange.202207410)
Unifying views on catalyst deactivation
A.J. Martín, S. Mitchell, C. Mondelli, S. Jaydev, J. Pérez-Ramírez
Nat. Catal. 2022, 5, 854-866 (doi:10.1038/s41929-022-00842-y)
A review of computational modeling techniques for wet waste valorization: research trends and future perspectives
J. Li, M. Suvarna, L. Li, L. Pan, J. Pérez-Ramírez, Y.S. Ok, X. Wang
J. Clean. Prod. 2022, 367, 133025 (doi:10.1016/j.jclepro.2022.133025)
Assessing the environmental benefit of palladium-based single-atom heterogeneous catalysts for Sonogashira coupling
D. Faust Akl, D. Poier, S.C. D’Angelo, T. Pinheiro Araújo, V. Tulus, O.V. Safonova, S. Mitchell, R. Marti, G. Guillén-Gosálbez, J. Pérez-Ramírez
Green Chem. 2022, 24, 6879-6888 (doi:10.1039/d2gc01853e, inside front cover)
Elucidation of metal local environments in single-atom catalysts based on carbon nitrides
S. Büchele, A. Yakimov, S.M. Collins, A. Ruiz-Ferrando, Z. Chen, E. Willinger, D.M. Kepaptsoglou, Q.M. Ramasse, C.R. Müller, O.V. Safonova, N. López, C. Copéret, J. Pérez-Ramírez, S. Mitchell
Small 2022, 18, 2202080 (doi:10.1002/smll.202202080)
Elucidation of radical- and oxygenate-driven paths in zeolite-catalyzed conversion of methanol and methyl chloride to hydrocarbons
A. Cesarini, S. Mitchell, G. Zichittella, M. Agrachev, S.P. Schmid, G. Jeschke, Z. Pan, A. Bodi, P. Hemberger, J. Pérez-Ramírez
Nat. Catal. 2022, 5, 605-614 (doi:10.1038/s41929-022-00808-0, read behind the paper)
A generalized machine learning framework to predict the space-time yield of methanol from thermocatalytic CO₂ hydrogenation
M. Suvarna, T. Pinheiro Araújo, J. Pérez-Ramírez
Appl. Catal. B 2022, 315, 121530 (doi:10.1016/j.apcatb.2022.121530)
Long-chain hydrocarbons via CO₂ electroreduction enabled by polarized nickel catalysts
Y. Zhou, A.J. Martín, F. Dattila, S. Xi, N. López, J. Pérez-Ramírez, B.S. Yeo
Nat. Catal. 2022, 5, 545-554 (doi:10.1038/s41929-022-00803-5, read behind the paper, highlighted in Chemistry World)
Automated image analysis for single-atom detection in catalytic materials by transmission electron microscopy
S. Mitchell, F. Parés, D. Faust Akl, S. Collins, D. Kepaptsoglou, Q. Ramasse, D. Garcia-Gasulla, J. Pérez-Ramírez, N. López
J. Am. Chem. Soc. 2022, 144, 8018-8029 (doi:10.1021/jacs.1c12466, highlighted by C&EN)
Performance descriptors of nanostructured metal catalysts for acetylene hydrochlorination
S.K. Kaiser, E. Fako, I. Surin, F. Krumeich, V.A. Kondratenko, E.V. Kondratenko, A.H. Clark, N. López, J. Pérez-Ramírez
Nat. Nanotechnol. 2022, 17, 606-612 (doi:10.1038/s41565-022-01105-4)
Ceria-supported gold nanoparticles as a superior catalyst for nitrous oxide production via ammonia oxidation
Z. Tang, I. Surin, A. Rasmussen, F. Krumeich, E.V. Kondratenko, V.A. Kondratenko, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2022, 61, e202200772 (doi:10.1002/anie.202200772, back cover)
Angew. Chem. 2022, 134, e202200772 (doi:10.1002/ange.202200772)
Controlled formation of dimers and spatially isolated atoms in bimetallic Au-Ru catalysts via carbon host functionalization
V. Giulimondi, S.K. Kaiser, A.J. Martín, S. Büchele, F. Krumeich, A.H. Clark, J. Pérez-Ramírez
Small 2022, 18, 2200224 (doi:10.1002/smll.202200224)
A step forward for PVC manufacture from natural gas
G. Zichittella, A.P. Ceruti, G. Guillén-Gosálbez, J. Pérez-Ramírez
Chem 2022, 8, 883-889 (doi:10.1016/j.chempr.2022.02.012)
Flame spray pyrolysis as a synthesis platform to assess metal promotion in In₂O₃-catalyzed CO₂ hydrogenation
T. Pinheiro Araújo, J. Morales-Vidal, T. Zou, R. García-Muelas, P.O. Willi, K.M. Engel, O.V. Safonova, D. Faust Akl, F. Krumeich, R.N. Grass, C. Mondelli, N. López, J. Pérez-Ramírez
Adv. Energy Mater. 2022, 12, 2103707 (doi:10.1002/aenm.202103707, front cover)
Single-atom heterogeneous catalysts for sustainable organic synthesis
G. Giannakakis, S. Mitchell, J. Pérez-Ramírez
Trends Chem. 2022, 4, 264-276 (doi:10.1016/j.trechm.2022.01.008)
Natural wood-based catalytic membrane microreactors for continuous hydrogen generation
K. Tu, S. Büchele, S. Mitchell, L. Stricker, C. Liu, C. Goldhahn, J. Allaz, Y. Ding, R. Günther, Z. Zhang, J. Sun, S. Stucki, G. Panzarasa, S. Zeeman, I. Burgert, J. Pérez-Ramírez, T. Keplinger
ACS Appl. Mater. Interfaces 2022, 14, 8417-8426 (doi:10.1021/acsami.1c22850)
Generalizing performance equations in heterogeneous catalysis from hybrid data and statistical learning
S. Pablo-García, A. Sabadell-Rendon, A.J. Saadun, S. Morandi, J. Pérez-Ramírez, N. López
ACS Catal. 2022, 12, 1581-1594 (doi:10.1021/acscatal.1c04345)
Synthesis of Florol via Prins cyclisation over heterogeneous catalysts
B. Lasne, P. Mäki-Arvela, A. Aho, Z. Vajglova, K. Eränen, N. Kumar, J. Sanchez-Velandia, M. Peurla, C. Mondelli, J. Pérez-Ramírez, D.Yu. Murzin
J. Catal. 2022, 405, 288-302 (doi:10.1016/j.jcat.2021.12.008)
ZnO-promoted inverse ZrO₂-Cu catalysts for CO₂ hydrogenation to methanol at mild conditions
T. Zou, T. Pinheiro Araújo, F. Krumeich, C. Mondelli, J. Pérez-Ramírez
ACS Sustainable Chem. Eng. 2022, 10, 81-90 (doi:10.1021/acssuschemeng.1c04751)
Mechanistic routes toward C3 products in copper-catalysed CO₂ electroreduction
S. Pablo-García, F.L.P. Veenstra, L.R.L. Ting, R. García-Muelas, A.J. Martín, F. Dattila, B.S. Yeo, J. Pérez-Ramírez, N. López
Catal. Sci. Technol. 2022, 12, 409-417 (doi:10.1039/D1CY01423D)
Atomic Pd-promoted ZnZrO_x solid solution catalyst for CO₂ hydrogenation to methanol
K. Lee, U. Anjum, T. Pinheiro Araújo, C. Mondelli, Q. He, S. Furukawa, J. Pérez-Ramírez, S.M. Kozlov, N. Yan
Appl. Catal. B 2022, 304, 120994 (doi:10.1016/j.apcatb.2021.120994)
Recent progress in materials exploration for thermocatalytic, photocatalytic, and integrated photothermocatalytic CO₂-to-fuel conversion
W. Zhang, D. Ma, J. Pérez-Ramírez, Z. Chen
Adv. Energy Sustainability Res. 2022, 3, 2100169 (doi:10.1002/aesr.202100169)
Redispersion strategy for high-loading carbon-supported metal catalysts with controlled nuclearity
V. Giulimondi, S.K. Kaiser, M. Agrachev, F. Krumeich, A.H. Clark, S. Mitchell, G. Jeschke, J. Pérez-Ramírez
J. Mater. Chem. A 2022, 10, 5953-5961 (doi:10.1039/D1TA09238C, inside front cover)
Carbon‑supported bimetallic ruthenium‑iridium catalysts for selective and stable hydrodebromination of dibromomethane
A.J. Saadun, S. Mitchell, H. Bonchev, J. Pérez-Ramírez
ChemCatChem 2022, 14, e202101494 (doi:10.1002/cctc.202101494, cover feature)
Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries
X. Hai, S. Xi, S. Mitchell, K. Harrath, H. Xu, D. Faust Akl, D. Kong, J. Li, Z. Li, T. Sun, H. Yang, Y. Cui, C. Su, X. Zhao, J. Li, J. Pérez-Ramírez, J. Lu
Nat. Nanotechnol. 2022, 17, 174-181 (doi:10.1038/s41565-021-01022-y)
Planetary metrics for the absolute environmental sustainability assessment of chemicals
V. Tulus, J. Pérez-Ramírez, G. Guillén-Gosálbez
Green Chem. 2021, 23, 9881-9893 (doi:10.1039/D1GC02623B, outside front cover)
Structure sensitivity of nitrogen‑doped carbon‑supported metal catalysts in dihalomethane hydrodehalogenation
A.J. Saadun, A. Ruiz-Ferrando, S. Büchele, D. Faust Akl, N. López, J. Pérez-Ramírez
J. Catal. 2021, 404, 291-305 (doi:10.1016/j.jcat.2021.10.008)
Toward reliable and accessible ammonia quantification in the electrocatalytic reduction of nitrogen
A.J. Martín, F.L.P. Veenstra, J. Lüthi, R. Verel, J. Pérez Ramírez
Chem Catal. 2021, 1, 1505-1518 (doi:10.1016/j.checat.2021.10.002, front cover)
Direct conversion of polypropylene into liquid hydrocarbons on carbon-supported platinum catalysts
S.D. Jaydev, A.J. Martín, J. Pérez-Ramírez
ChemSusChem 2021, 14, 5179-5185 (doi:10.1002/cssc.202101999, cover feature, VIP article, highlighted by ChemistryViews, C&EN)
Functionalized wood with tunable tribo-polarity for efficient triboelectric nanogenerators
J. Sun, K. Tu, S. Büchele, S.M. Koch, Y. Ding, S.N. Ramakrishna, S. Stucki, H. Guo, C. Wu, T. Keplinger, J. Pérez-Ramírez, I. Burgert, G. Panzarasa
Matter 2021, 4, 3049-3066 (doi:10.1016/j.matt.2021.07.022)
Sustainability assessment of thermocatalytic conversion of CO₂ to transportation fuels, methanol, and 1-propanol
C.H. Vo, C. Mondelli, H. Hamedi, J. Pérez-Ramírez, S. Farooq, I. Karimi
ACS Sustainable Chem. Eng. 2021, 9, 10591-10600 (doi:10.1021/acssuschemeng.1c02805)
Ethane-based catalytic process for vinyl chloride manufacture
G. Zichittella, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2021, 60, 24089-24095 (doi:10.1002/ange.202105851, hot paper, back cover)
Angew. Chem. 2021, 133, 24291-24297 (doi:10.1002/ange.202105851, back cover)
Design of carbon supports for metal-catalyzed acetylene hydrochlorination
S.K. Kaiser, I. Surin, A. Amorós-Pérez, S. Büchele, F. Krumeich, A.H. Clark, M.C. Román-Martínez, M.A. Lillo-Rodenas, J. Pérez-Ramírez
Nat. Commun. 2021, 12:4016 (doi:10.1038/s41467-021-24330-2)
Atomically precise control in the design of low-nuclearity supported metal catalysts
S. Mitchell, J. Pérez-Ramírez
Nat. Rev. Mater. 2021, 6, 969-985 (doi:10.1038/s41578-021-00360-6, front cover)
Planetary boundaries analysis of low-carbon ammonia production routes
S.C. D’Angelo, S. Cobo, V. Tulus, A. Nabera, A. Martín, J. Pérez-Ramírez, G.Guillén-Gosálbez
ACS Sustainable Chem. Eng. 2021, 9, 9740-9749 (doi:10.1021/acssuschemeng.1c01915)
Methanol synthesis via hydrogenation of hybrid CO₂-CO feeds
T. Pinheiro Araújo, A.H. Hergesell, D. Faust Akl, S. Büchele, J.A. Stewart, C. Mondelli, J. Pérez-Ramírez
ChemSusChem 2021, 14, 2914-2923 (doi:10.1002/cssc.202100859)
A quantitative roadmap for China towards carbon neutrality in 2060 using methanol and ammonia as energy carriers
Y. Li, S. Lan, M. Ryberg, J. Pérez-Ramírez, X. Wang
iScience 2021, 24, 102513 (doi:10.1016/j.isci.2021.102513)
Precursor nuclearity and ligand effects in atomically-dispersed heterogeneous iron catalysts for alkyne semi-hydrogenation
D. Faust Akl, A. Ruiz-Ferrando, E. Fako, R. Hauert, O. Safonova, S. Mitchell, N. López, J. Pérez-Ramírez
ChemCatChem 2021, 13, 3247-3256 (doi:10.1002/cctc.202100235)
Impact of heteroatom speciation on the activity and stability of carbon-based catalysts for propane dehydrogenation
S. Büchele, G. Zichittella, S. Kanatakis, S. Mitchell, J. Pérez-Ramírez
ChemCatChem 2021, 13, 2599-2608 (doi:10.1002/cctc.202100208, cover feature)
Sustainability footprints of a renewable carbon transition for the petrochemical sector within planetary boundaries
Á. Galán-Martín, V. Tulus, I. Díaz, C. Pozo, J. Pérez-Ramírez, G. Guillén-Gosálbez
One Earth 2021, 4, 565-583 (doi:10.1016/j.oneear.2021.04.001)
Nanostructure of nickel-promoted indium oxide catalysts drives selectivity in CO₂ hydrogenation
M.S. Frei, C. Mondelli, R. García-Muelas, J. Morales-Vidal, M. Philipp, O.V. Safonova, N. López, J.A. Stewart, D. Curulla Ferré, J. Pérez-Ramírez
Nat. Commun. 2021, 12:1960 (doi:10.1038/s41467-021-22224-x, highlighted in Nat. Catal.)
Process modelling and life cycle assessment coupled with experimental work to shape the future sustainable production of chemicals and fuels
I. Ioannou, S.C. D’Angelo, Á. Galán-Martín, C. Pozo, J. Pérez-Ramírez, G. Guillén-Gosálbez
React. Chem. Eng. 2021, 6, 1111-1286 (doi:10.1039/D0RE00451K, outside front cover)
Microfabrication enables quantification of interfacial activity in thermal catalysis
M.S. Frei, F.L.P. Veenstra, D. Capeder, J.A. Stewart, D. Curulla-Ferré, A.J. Martín, C. Mondelli, J. Pérez-Ramírez
Small Methods 2021, 5, 2001231 (doi:10.1002/smtd.202001231, inside back cover)
Status and prospects of decentralised natural gas valorisation to energy and energy carriers
G. Zichittella, J. Pérez-Ramírez
Chem. Soc. Rev. 2021, 50, 2984-3012 (doi:10.1039/d0cs01506g, front cover)
Upscaling effects on alkali metal-grafted ultrastable Y zeolite extrudates for modeled catalytic deoxygenation of bio-oils
A.M. Hernández-Giménez, L.M. de Kort, G.T. Whiting, H. Hernando, B. Puértolas, J. Pérez-Ramírez, D.P. Serrano, P.C.A. Bruijnincx, B.M. Weckhuysen
ChemCatChem 2021, 13, 1951-1965 (doi:10.1002/cctc.202001840)
Impact of hybrid CO₂-CO feeds on methanol synthesis over In₂O₃-based catalysts
T. Pinheiro Araújo, A. Shah, C. Mondelli, J.A. Stewart, D. Curulla-Ferré, J. Pérez-Ramírez
Appl. Catal. B 2021, 285, 119878 (doi:10.1016/j.apcatb.2021.119878)
Catalytic processing of plastic waste on the rise
A.J. Martín, C. Mondelli, S.D. Jaydev, J. Pérez-Ramírez
Chem 2021, 7, 1487-1533 (doi:10.1016/j.chempr.2020.12.006)
Nuclearity and host effects of carbon-supported platinum catalysts for dibromomethane hydrodebromination
A.J. Saadun, S.K. Kaiser, A. Ruiz-Ferrando, S. Pablo-García, S. Büchele, E. Fako, N. López, J. Pérez Ramírez
Small 2021, 17, 2005234 (doi:10.1002/smll.202005234)
Quantification of redox sites during catalytic propane oxychlorination by operando EPR spectroscopy
G. Zichittella, Y. Polyhach, R. Tschaggelar, G. Jeschke, J. Pérez Ramírez
Angew. Chem. Int. Ed. 2021, 60, 3596-3602 (doi:10.1002/anie.202013331, inside cover)
Angew. Chem. 2021, 133, 3640-3646 (doi:10.1002/ange.202013331)
Sustainable synthesis of bimetallic single atom gold-based catalysts with enhanced durability in acetylene hydrochlorination
S.K. Kaiser, A.H. Clark, L. Cartocci, F. Krumeich, J. Pérez-Ramírez
Small 2021, 17, 2004599 (doi:10.1002/smll.202004599, front cover)
Biomass valorisation over polyoxometalate-based catalysts
J. Zhong, J. Pérez-Ramírez, N. Yan
Green Chem. 2021, 23, 18-36 (doi:10.1039/D0GC03190A, inside front cover)
Nanoscale engineering of catalytic materials for sustainable technologies
S. Mitchell, R. Qin, N. Zheng, J. Pérez-Ramírez
Nat. Nanotechnol. 2021, 16, 129-139 (doi:10.1038/s41565-020-00799-8, front cover)
Design of local atomic environments in single-atom electrocatalysts for renewable energy conversions
T. Sun, S. Mitchell, J. Li, P. Lyu, X.B. Wu, J. Pérez-Ramírez, J. Lu
Adv. Mater. 2021, 33, 2003075 (doi:10.1002/adma.202003075)
Activity differences of rutile and anatase TiO₂ polymorphs in catalytic HBr oxidation
V. Paunović, M. Rellán, N. López, J. Pérez-Ramírez
Catal. Today 2021, 369, 221-226 (doi:10.1016/j.cattod.2020.03.036)
Achieving low-carbon future through the Energy-Chemical Nexus in China
Y. Li, S. Lan, J. Pérez-Ramírez, X. Wang
Sustain. Energy Fuels 2020, 4, 6141-6155 (doi:10.1039/D0SE01337D)
Key role of chemistry versus bias in electrocatalytic oxygen evolution
H.N. Nong, L.J. Falling, A. Bergmann, M. Klingenhof, H.P. Tran, C. Spöri, R. Mom, J. Timoshenko, G. Zichittella, A. Knop-Gericke, S. Piccinin, J. Pérez-Ramírez, B. Roldan Cuenya, R. Schlögl, P. Strasser, D. Teschner, T.E. Jones
Nature 2020, 587, 408-413 (doi:10.1038/s41586-020-2908-2, highlighted by ETH News, Chemistry World)
Single-atom heterogeneous catalysts across the periodic table
S.K. Kaiser, Z. Chen, D. Faust Akl, S. Mitchell, J. Pérez-Ramírez
Chem. Rev. 2020, 120, 11703-11809 (doi:10.1021/acs.chemrev.0c00576, front cover)
Challenges and opportunities in synthesizing high volume chemicals from CO₂ without direct H₂ input
L. Tao, T.S. Choksi, W. Liu, J. Pérez-Ramírez
ChemSusChem 2020, 13, 6066-6089 (doi:10.1002/cssc.202001604, cover feature)
Activation of copper species on carbon nitride for enhanced activity in the arylation of amines
E. Vorobyeva, V.C. Gerken, S. Mitchell, A. Sabadell-Rendón, R. Hauert, S. Xi, A. Borgna, D. Klose, S.M. Collins, P.A. Midgley, D.M. Kepaptsoglou, Q.M. Ramasse, A. Ruiz-Ferrando, E. Fako, M.A. Ortuño, N. López, E.M. Carreira, J. Pérez-Ramírez
ACS Catal. 2020, 10, 11069-11080 (doi:10.1021/acscatal.0c03164)
Single atom catalysis: a decade of stunning progress and the promise for a bright future
S. Mitchell, J. Pérez-Ramírez
Nat. Commun. 2020, 11:4302 (doi:10.1038/s41467-020-18182-5)
Electrochemical reduction of carbon dioxide to 1-butanol on oxide-derived copper
L.R.L. Ting, R. García-Muelas, A.J. Martín, F.L.P. Veenstra, S.T.-J. Chen, Y. Peng, E.Y.X. Per, S. Pablo-García, N. López, J. Pérez-Ramírez, B.S. Yeo
Angew. Chem. Int. Ed. 2020, 59, 21072-21079 (doi:10.1002/anie.202008289)
Angew. Chem. 2020, 132, 21258-21265 (doi:10.1002/ange.202008289)
Methanol as a hydrogen carrier: kinetic and thermodynamic drivers for its CO₂-based synthesis and reforming over heterogeneous catalysts
M.S. Frei, C. Mondelli, M. Short, J. Pérez-Ramírez
ChemSusChem 2020, 13, 6330-6337 (doi:10.1002/cssc.202001518, cover feature)
Enhanced performance of zirconium-doped ceria catalysts for the methoxycarbonylation of anilines
J.L. Núñez-Rico, M. Rellán-Piñeiro, B. Puértolas, A. Vidal-Ferran, N. López, J. Pérez-Ramírez, S. Wershofen
Chem. Eur. J. 2020, 26, 16129-16137 (doi:10.1002/chem.202003201)
Hybridization of fossil and CO₂-based routes for ethylene production using renewable energy
I. Ioannou, S.C. D'Angelo, A.J. Martín, J. Pérez-Ramírez, G. Guillén-Gosálbez
ChemSusChem 2020, 13, 6370-6380 (doi:10.1002/cssc.202001312)
Carrier induced modification of palladium nanoparticles on porous boron nitride for alkyne semi-hydrogenation
S. Büchele, Z. Chen, E. Fako, F. Krumeich, R. Hauert, O.V. Safonova, N. López, S. Mitchell, J. Pérez‐Ramírez
Angew. Chem. Int. Ed. 2020, 59, 19639-19644 (doi:10.1002/anie.202005842)
Angew. Chem. 2020, 139, 19807-19812 (doi: 10.1002/ange.202005842)
Substrate substitution effects in the Fries rearrangement of aryl esters over zeolite catalysts
R. Lin, S. Mitchell, T. Netscher, J. Medlock, R.T. Stemmler, W. Bonrath, U. Létinois, J. Pérez Ramírez
Catal. Sci. Technol. 2020, 10, 4282-4292 (doi:10.1039/D0CY00590H)
Transformation of titanium carbide into mesoporous titania for catalysed HBr oxidation
K.J. Stephens, G. Zichittella, A.J. Saadun, S. Büchele, B. Puértolas, R. Verel, F. Krumeich, M.G. Willinger, J. Pérez-Ramírez
Catal. Sci. Technol. 2020, 10, 4072-4083 (doi:10.1039/D0CY00805B)
Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeolite
M. Azkaar, Z. Vajglova, P. Mäki-Arvela, A. Aho, N. Kumar, H. Palonen, K. Eränen, M. Peurla, L. Kulikov, A. Maximov, C. Mondelli, J. Pérez-Ramírez, D. Yu. Murzin
Fuel 2020, 278, 118193 (doi:10.1016/j.fuel.2020.118193)
Biomass valorisation over metal-based solid catalysts from nanoparticles to single atoms
C. Mondelli, G. Gözaydın, N. Yan, J. Pérez-Ramírez
Chem. Soc. Rev. 2020, 49, 3764-3782 (doi:10.1039/D0CS00130A)
Tunable catalytic performance of palladium nanoparticles for H₂O₂ direct synthesis via surface-bonded ligands
L.F. de Lima e Freitas, B. Puértolas, J. Zhang, B. Wang, A.S. Hoffman, S.R. Bare, J. Pérez-Ramírez, J.W. Medlin, E. Nikolla
ACS Catal. 2020, 10, 5202-5207 (doi:10.1021/acscatal.0c01517)
Performance of metal-catalyzed hydrodebromination of dibromomethane analyzed by descriptors derived from statistical learning
A.J. Saadun, S. Pablo-Garcia, V. Paunović, Q. Li, A. Sabadell-Rendón, K. Kleemann, F. Krumeich, N. López, J. Pérez-Ramírez
ACS Catal. 2020, 10, 6129-6143 (doi:10.1021/acscatal.0c00679, cover)
Selectivity patterns in the electrocatalytic reduction of CO₂ revealed by laser-microstructured copper
F.L.P. Veenstra, N. Ackerl, A.J. Martín, J. Pérez-Ramírez
Chem 2020, 6, 1707-1722 (doi:10.1016/j.chempr.2020.04.001)
Core-shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO₂
S. Das, J. Pérez-Ramírez, J. Gong, N. Dewangan, K. Hidajat, B.C. Gates, S. Kawi
Chem. Soc. Rev. 2020, 49, 2937-3004 (doi:10.1039/C9CS00713J, inside back cover)
New analytical tools for advanced mechanistic studies in catalysis: photoionization and photoelectron photoion coincidence spectroscopy
P. Hemberger, J.A. van Bokhoven, J. Pérez-Ramírez, A. Bodi
Catal. Sci. Technol. 2020, 10, 1975-1990 (doi:10.1039/C9CY02587A, inside front cover)
Structure sensitivity and evolution of nickel-bearing nitrogen-doped carbons in the electrochemical reduction of CO₂
S. Büchele, A.J. Martín, S. Mitchell, F. Krumeich, S.M. Collins, S. Xi, A. Borgna, J. Pérez-Ramírez
ACS Catal. 2020, 10, 3444-3454 (doi:10.1021/acscatal.9b05333)
Nanostructuring unlocks high performance of platinum single-atom catalysts for stable vinyl chloride production
S.K. Kaiser, E. Fako, G. Manzocchi, F. Krumeich, R. Hauert, A.H. Clark, O.V. Safonova, N. López, J. Pérez-Ramírez
Nat. Catal. 2020, 3, 376-385 (doi:10.1038/s41929-020-0431-3, front cover, highlighted in Chemistry World)
Green synthesis of hierarchical metal-organic framework/wood functional composites with superior mechanical properties
K. Tu, B. Puértolas, M. Adobes-Vidal, Y. Wang, J. Sun, J. Traber, I. Burgert, J. Pérez-Ramírez, T. Keplinger
Adv. Sci. 2020, 7, 1902897 (doi:10.1002/advs.201902897, back cover)
CO₂-promoted catalytic process forming higher alcohols with tunable nature at record productivity
H.T. Luk, G. Novak, O.V. Safonova, S. Siol, J.A. Stewart, D. Curulla Ferré, C. Mondelli, J. Pérez-Ramírez
ChemCatChem 2020, 12, 2732-2744 (doi:10.1002/cctc.202000059, front cover)
Operando photoelectron photoion coincidence spectroscopy unravels mechanistic fingerprints of propane activation by catalytic oxyhalogenation
G. Zichittella, P. Hemberger, F. Holzmeier, A. Bodi, J. Pérez-Ramírez
J. Phys. Chem. Lett. 2020, 11, 856-863 (doi:10.1021/acs.jpclett.9b03836)
Nitrogen-doped carbons with hierarchical porosity via chemical blowing towards long-lived metal-free catalysts for acetylene hydrochlorination
S.K. Kaiser, K.S. Song, S. Mitchell, A. Coskun, J. Pérez Ramírez
ChemCatChem 2020, 12, 1922-1925 (doi:10.1002/cctc.201902331, front cover)
Role of zirconia in indium oxide-catalyzed CO₂ hydrogenation to methanol
M.S. Frei, C. Mondelli, A. Cesarini, F. Krumeich, R. Hauert, J.A. Stewart, D. Curulla Ferre, J. Pérez-Ramírez
ACS Catal. 2020, 10, 1133-1145 (doi:10.1021/acscatal.9b03305)
Aluminum redistribution in ZSM-5 zeolite upon interaction with gaseous halogens and hydrogen halides and implications in catalysis
V. Paunović, S. Mitchell, R. Verel, S.S. Lee, J. Pérez-Ramírez
J. Phys. Chem. C 2020, 1, 722-733 (doi:10.1021/acs.jpcc.9b09984)
Dual catalyst system for selective vinyl chloride production via ethene oxychlorination
M. Scharfe, V. Paunović, S. Mitchell, R. Hauert, S. Xi, A. Borgna, J. Pérez-Ramírez
Catal. Sci. Technol. 2020, 10, 560-575 (doi:10.1039/C9CY01801H)
Epitaxially-directed iridium nanostructures on titanium dioxide for the selective hydrodechlorination of dichloromethane
A.J. Saadun, G. Zichittella, V. Paunović, B.A. Markaide-Aiastui, S. Mitchell, J. Pérez-Ramírez
ACS Catal. 2020, 10, 528-542 (doi:10.1021/acscatal.9b04467)
Ceria in halogen chemistry
M. Scharfe, G. Zichittella, V. Paunović, J. Pérez-Ramírez
Chin. J. Catal. 2020, 41, 915-927 (doi:10.1016/S1872-2067(19)63528-X)
Alkane functionalization via catalytic oxychlorination: performance as a function of the carbon number
G. Zichittella, J. Lüthi, V. Paunović, J. Pérez-Ramírez
Energy Technol. 2020, 8, 1900622 (doi:10.1002/ente.201900622)
Cascade deoxygenation process integrating acid and base catalysts for the efficient production of second-generation biofuels
H. Hernando, B. Puértolas, P. Pizarro, J. Fermoso, J. Pérez-Ramírez, D.P. Serrano
ACS Sustainable Chem. Eng. 2019, 7, 18027-18037 (doi:10.1021/acssuschemeng.9b04921)
The volcano trend in electrocatalytic CO₂ reduction activity over atomically-dispersed metal sites on nitrogen-doped carbon
J. Li, P. Prslja, T. Shinagawa, A.J. Martin, F. Krumeich, K. Artyushkova, P. Atanassov, A. Zitolo, Y. Zhou, R. García-Muelas, N. López, J. Pérez-Ramírez, F. Jaouen
ACS Catal. 2019, 9, 10426-10439 (doi:10.1021/acscatal.9b02594)
Plant-to-planet analysis of CO₂-based methanol processes
A. González-Garay, M.S. Frei, A. Al-Qahtani, C. Mondelli, G. Guillén-Gosálbez, J. Pérez-Ramírez
Energy Environ. Sci. 2019, 12, 3425-3436 (doi:10.1039/C9EE01673B, inside back cover)
Strategies to break linear scaling relationships
J. Pérez-Ramírez, N. López
Nat. Catal. 2019, 2, 971-976 (doi:10.1038/s41929-019-0376-6)
Transforming energy with single-atom catalysts
S. Ding, M.J. Hülsey, J. Pérez-Ramírez, N. Yan
Joule 2019, 3, 2897-2929 (doi:10.1016/j.joule.2019.09.015)
Heading to distributed electrocatalytic conversion of small abundant molecules into fuels, chemicals, and fertilizers
A.J. Martín, J. Pérez-Ramírez
Joule 2019, 3, 2602-2621 (doi:10.1016/j.joule.2019.09.007)
Mechanistic insights into the ceria-catalyzed synthesis of carbamates as polyurethane precursors
B. Puértolas, M. Rellán-Piñeiro, J.L. Núñez-Rico, A.P. Amrute, A. Vidal-Ferran, N. Lopez, J. Pérez-Ramírez, S. Wershofen
ACS Catal. 2019, 9, 7708-7720 (doi:10.1021/acscatal.9b02086)
Mechanistic origin of the diverging selectivity patterns in catalyzed ethane and ethene oxychlorination
M. Scharfe, G. Zichittella, V.A. Kondratenko, E.V. Kondratenko, N. López, J. Pérez-Ramírez
J. Catal. 2019, 377, 233-244 (doi:10.1016/j.jcat.2019.07.021)
Preparation of highly active phosphated TiO₂ catalysts via continuous sol-gel synthesis in a microreactor
O. Martin, N. Bolzli, B. Puértolas, J. Pérez-Ramírez, P. Riedlberger
Catal. Sci. Technol. 2019, 9, 4744-4758 (doi:10.1039/c8cy02574f)
Preserved in a shell: High-performance graphene-confined ruthenium nanoparticles in acetylene hydrochlorination
S.K. Kaiser, R. Lin, F. Krumeich, O.V. Safonova, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2019, 58, 12297-12304 (doi:10.1002/anie.201906916)
Angew. Chem. 2019, 131, 12425-12432 (doi:10.1002/ange.201906916)
Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO₂ hydrogenation
M.S. Frei, C. Mondelli, R. Garcia-Muelas, K.S. Kley, B. Puértolas, N. López, O. Safonova, J.A. Stewart, D. Curulla Ferré, J. Pérez-Ramírez
Nat. Commun. 2019, 10:3377 (doi:10.1038/s41467-019-11349-9)
Nitride-derived copper modified with indium as a selective and highly stable catalyst for the electroreduction of carbon dioxide
F.L.P. Veenstra, A.J. Martín, J. Pérez-Ramírez
ChemSusChem 2019, 12, 3501-3508 (doi:10.1002/cssc.201901309, very important paper, cover feature)
Catalytic halogenation of methane: a dream reaction with practical scope?
V. Paunović, J. Pérez-Ramírez
Catal. Sci. Technol. 2019, 9, 4515-4530 (doi:10.1039/C9CY00625G, hot article, outside front cover)
Selective propylene production via propane oxychlorination on metal phosphate catalysts
G. Zichittella, S. Stähelin, F. Goedicke, J. Pérez-Ramírez
ACS Catal. 2019, 9, 5772-5782 (doi:10.1021/acscatal.9b01315)
Tailoring nitrogen-doped carbons as hosts for single-atom catalysts
S. Büchele, Z. Chen, S. Mitchell, R. Hauert, F. Krumeich, J. Pérez-Ramírez
ChemCatChem 2019, 11, 2812-2820 (doi:10.1002/cctc.201900547, top downloaded paper)
Atom-by-atom resolution of structure-function relations over low-nuclearity metal catalysts
E. Vorobyeva, E. Fako, Z. Chen, S.M. Collins, D. Johnstone, P.A. Midgley, R. Hauert, O.V. Safonova, G. Vilé, N. López, S. Mitchell, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2019, 58, 8724-8729 (doi:10.1002/anie.201902136, hot paper, highlighted in ChemViews))
Angew. Chem. 2019, 131, 8816-8821 (doi:10.1002/ange.201902136)
Sustainable continuous flow valorization of γ‐valerolactone with trioxane to α‐methylene‐γ‐valerolactone over basic beta zeolite
M. Al-Naji, B. Puértola, B. Kumru, D. Cruz, M. Bäumel, B.V.K.J. Schmidt, N.V. Tarakina, J. Pérez‐Ramírez
ChemSusChem 2019, 12, 2628-2636 (doi:10.1002/cssc.201900418, cover feature)
Kinetics of ceria-catalysed ethene oxychlorination
Z. Vajglova, R. Hemery, N. Kumar, K. Eränen, M. Peurla, J. Peltonen, J. Wärnå, J. Pérez-Ramírez, T. Salmi, D. Yu. Murzin
J. Catal. 2019, 372, 287-298 (doi:10.1016/j.jcat.2019.03.009)
Impact of carrier acidity on the conversion of syngas to higher alcohols over zeolite-supported copper-iron catalysts
H.T. Luk, C. Mondelli, S. Mitchell, D. Curulla Ferré, J.A. Stewart, J. Pérez-Ramírez
J. Catal. 2019, 371, 116-125 (doi:10.1016/j.jcat.2019.01.021)
Tunability and scalability of single-atom catalysts based on carbon nitride
Z. Chen, S. Mitchell, F. Krumeich, R. Hauert, S. Yakunin, M.V. Kovalenko, J. Pérez-Ramírez
ACS Sustainable Chem. Eng. 2019, 7, 5223-5230 (doi:10.1021/acssuschemeng.8b06148)
Halogen-dependent surface confinement governs selective alkane functionalization to olefins
G. Zichittella, M. Scharfe, B. Puértolas, V. Paunović, P. Hemberger, A. Bodi, L. Szentmiklósi, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2019, 58, 5877-5881 (doi:10.1002/anie.201811669, hot paper, front cover, highlighted in ChemViews)
Angew. Chem. 2019, 131, 5935-5940 (doi:10.1002/ange.201811669)
Selective methane functionalization via oxyhalogenation over supported noble metal nanoparticles
V. Paunović, G. Zichittella, P. Hemberger, A. Bodi, J. Pérez-Ramírez
ACS Catal. 2019, 9, 1710-1725 (doi:10.1021/acscatal.8b04375)
Controlling the speciation and reactivity of carbon-supported gold nanostructures for catalysed acetylene hydrochlorination
S. Kaiser, R. Lin, S. Mitchell, E. Fako, F. Krumeich, R. Hauert, O.V. Safonova, V.A. Kondratenko, E.V. Kondratenko, S.M. Collins, P.A. Midgley, N. López, J. Pérez-Ramírez
Chem. Sci. 2019, 10, 359-369 (doi:10.1039/C8SC03186J, inside front cover)
Design of single gold atoms on nitrogen-doped carbon for molecular recognition in alkyne semi-hydrogenation
R. Lin, D. Albani, E. Fako, S.K. Kaiser, O.V. Safonova, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2019, 58, 504-509 (doi:10.1002/anie.201805820, hot paper, front cover)
Angew. Chem. 2019, 131, 514-519 (doi:10.1002/ange.201805820)
Ensemble design in nickel phosphide catalysts for alkyne semi-hydrogenation
D. Albani, K. Karajovic, B. Tata, Q. Li, S. Mitchell, N. López, J. Pérez-Ramírez
ChemCatChem 2019, 11, 457-464 (doi:10.1002/cctc.201801430, cover feature)
Electrocatalytic reduction of nitrogen: from Haber-Bosch to ammonia artificial leaf
A.J. Martín, T. Shinagawa, J. Pérez-Ramírez
Chem 2019, 5, 263-283 (doi:10.1016/j.chempr.2018.10.010)
Origin of the selective electroreduction of carbon dioxide to formate by chalcogen modified copper
R. García-Muelas, F. Dattila, T. Shinagawa, A.J. Martín, J. Pérez-Ramírez, N. López
J. Phys. Chem. Lett. 2018, 9, 7153-7159 (doi:10.1021/acs.jpclett.8b03212)
Techno-economic analysis of a glycerol biorefinery
S.C. D'Angelo, A. Dall'Ara, C. Mondelli, J. Pérez-Ramírez, S. Papadokonstantakis
ACS Sustainable Chem. Eng. 2018, 6, 16563-16572 (doi:10.1021/acssuschemeng.8b03770)
Hydrotalcite-derived mixed oxides for the synthesis of a key vitamin A intermediate reducing waste
F.J.A.G. Coumans, S. Mitchell, J. Schütz, J. Medlock, J. Pérez Ramírez
ACS Omega 2018, 3, 15293-15301 (doi:10.1021/acsomega.8b02234)
Role of carbonaceous supports and potassium promoter on higher alcohols synthesis over copper-iron catalysts
H.T. Luk, C. Mondelli, S. Mitchell, S. Siol, J.A. Stewart, D. Curulla Ferre, J. Pérez-Ramírez
ACS Catal. 2018, 8, 9604-9618 (doi:10.1021/acscatal.8b02714)
Shedding new light on nanostructured catalysts with positron annihilation spectroscopy
S. Mitchell, L. Gerchow, R. Warringham, P. Crivelli, J. Pérez-Ramírez
Small Methods 2018, 2, 1800268 (doi:10.1002/smtd.201800268, back cover)
The multifaceted reactivity of single-atom heterogeneous catalysts
S. Mitchell, E. Vorobyeva, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2018, 57, 15316–15329 (doi:10.1002/anie.201806936, frontispiece, top downloaded paper)
Angew. Chem. 2018, 130, 15538–15552 (doi:10.1002/ange.201806936)
Enhanced base‐free formic acid production from CO₂ on Pd/g‐C₃N₄ by tuning of the carrier defects
C. Mondelli, B. Puértolas, M. Ackermann, Z.Chen, J. Pérez-Ramírez
ChemSusChem 2018, 11, 2859-2869 (doi:10.1002/cssc.201801362, front cover, top downloaded paper)
Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation
D. Albani, M. Shahrokhi, Z. Chen, S. Mitchell, R. Hauert, N. López, J. Pérez-Ramírez
Nat. Commun. 2018, 9:2634 (doi:10.1038/s41467-018-05052-4, read behind the paper)
A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling
Z. Chen, E. Vorobyeva, S. Mitchell, E. Fako, M.A. Ortuño, N. López, S.M. Collins, P.A. Midgley, S. Richard, G. Vilé, J. Pérez-Ramírez
Nat. Nanotechnol. 2018, 13, 702-707 (doi:10.1038/s41565-018-0167-2, highlighted by ETH News, C&EN, Nature Catalysis)
Structure-performance descriptors and the role of Lewis acidity in the methanol-to-propylene process
I. Yarulina, S. Bailleul, K. De Wispelaere, J. Goetzer, M. Radersma, E. Abou-Hamad, I. Vollmer, M. Goesten, B. Mezari, E.J.M. Hensen, J.S. Martínez-Espín, M. Morten, S. Mitchell, J. Pérez-Ramírez, U. Olsbye, B.M. Weckhuysen, V. Van Speybroeck, F. Kapteijn, J. Gascon
Nat. Chem. 2018, 10, 804-812 (doi:10.1038/s41557-018-0081-0, cover, read behind the paper)
Single-atom heterogeneous catalysts based on distinct carbon nitride scaffolds
Z. Chen, E. Vorobyeva, S. Mitchell, E. Fako, N. López, S.M. Collins, R.K. Leary, P.A. Midgley, R. Hauert, J. Pérez-Ramírez
Natl. Sci. Rev. 2018, 5, 642-652 (doi:10.1093/nsr/nwy048, highlighted by the WeChat platform cailiaoren, Eurekalert, Nanowerk News, and Science Newsline)
Evidence of radical chemistry in catalytic methane oxybromination
V. Paunović, P. Hemberger, A. Bodi, N. López, J. Pérez-Ramírez
Nat. Catal. 2018, 1, 363-370 (doi:10.1038/s41929-018-0071-z)
Lanthanum vanadate catalysts for selective and stable methane oxybromination
V. Paunović, M. Artusi, R. Verel, F. Krumeich, R. Hauert, J. Pérez-Ramírez
J. Catal. 2018, 363, 69-80 (doi:10.1016/j.jcat.2018.04.001)
Halogen type as a selectivity switch in catalysed alkane oxyhalogenation
G. Zichittella, B. Puértolas, V. Paunović, T. Block, R. Pöttgen, J. Pérez-Ramírez
Catal. Sci. Technol. 2018, 8, 2231-2243 (doi:10.1039/C8CY00122G)
Microfabricated electrodes unravel the role of interfaces in multicomponent copper-based CO₂ reduction catalysts
G.O. Larrazábal, T. Shinagawa, A.J. Martín, J. Pérez-Ramírez
Nat. Commun. 2018, 9:1477 (doi:10.1038/s41467-018-03980-9, highlighted in C&EN)
Mechanism and microkinetics of methanol synthesis via CO₂ hydrogenation on indium oxide
M.S. Frei, M. Capdevila-Cortada, R. García-Muelas, C. Mondelli, N. López, J.A. Stewart, D. Curulla-Ferré, J. Pérez-Ramírez
J. Catal. 2018, 361, 313-321 (doi:10.1016/j.jcat.2018.03.014)
Environmental and economical perspectives of a glycerol biorefinery
G.M. Lari, G. Pastore, M. Haus, Y. Ding, S. Papadokonstantakis, C. Mondelli, J. Pérez-Ramírez
Energy Environ. Sci. 2018, 11, 1012-1029 (doi:10.1039/C7EE03116E, front cover, hot article)
Mechanism of ethylene oxychlorination on ceria
M. Scharfe, M. Capdevila-Cortada, V.A. Kondratenko, E.V. Kondratenko, S. Colussi, A. Trovarelli, N. López, J. Pérez-Ramírez
ACS Catal. 2018, 8, 2651-2663 (doi:10.1021/acscatal.7b04431)
Acidity effects in positron annihilation lifetime spectroscopy of zeolites
R. Warringham, L. Gerchow, D. Cooke, P. Crivelli, R. Vallery, S. Mitchell, J. Pérez-Ramírez
J. Phys. Chem. C 2018, 122, 3443-3453 (doi:10.1021/acs.jpcc.7b11336)
Descriptors for high-performance nitrogen-doped carbon catalysts in acetylene hydrochlorination
R. Lin, S.K. Kaiser, R. Hauert, J. Pérez-Ramírez
ACS Catal. 2018, 8, 1114-1121 (doi:10.1021/acscatal.7b03031)
Sulfur-modified copper catalysts for the electrochemical reduction of carbon dioxide to formate
T. Shinagawa, G.O. Larrazábal, A.J. Martín, F. Krumeich, J. Pérez-Ramírez
ACS Catal. 2018, 8, 837-844 (doi:10.1021/acscatal.7b03161)
Activated TiC-SiC composite for natural gas upgrading via catalytic oxyhalogenation
G. Zichittella, B. Puértolas, S. Siol, V. Paunović, S. Mitchell, J. Pérez-Ramírez
ChemCatChem 2018, 10, 1282-1290 (doi:10.1002/cctc.201701632, cover feature)
Selective methane oxybromination over nanostructured ceria catalysts
V. Paunović, G. Zichittella, S. Mitchell, R. Hauert, J. Pérez-Ramírez
ACS Catal. 2018, 8, 291-303 (doi:10.1021/acscatal.7b03074)
Elucidating the distribution and speciation of boron and cesium in BCsX zeolite catalysts for styrene production
A.J. Martín, S. Mitchell, O. Scholder, R. Verel, R. Hauert, L. Bernard, C. Jensen, M. Schwefer, J. Pérez-Ramírez
ChemPhysChem 2018, 19, 437-445 (doi:10.1002/cphc.201701086)
Carbon nanofibres-supported KCoMo catalysts for syngas conversion into higher alcohols
H.T. Luk, T. Forster, C. Mondelli, S. Siol, D. Curulla Ferré, J. A. Stewart, J. Pérez-Ramírez
Catal. Sci. Technol. 2018, 8, 187-200 (doi:10.1039/C7CY01908D)
Towards a green manufacture of epichlorohydrin from glycerol using hydrotalcite-derived basic oxides
G.M. Lari, G. Pastore, C. Mondelli, J. Pérez-Ramírez
Green Chem. 2018, 20, 148-159 (doi:10.1039/C7GC02610B, front cover)
Determining bio-oil composition via chemometric tools based on infrared spectroscopy
T. García, A. Veses, J.M. López, B. Puértolas, J. Pérez-Ramírez, M.S. Callén
ACS Sustainable Chem. Eng. 2017, 5, 8710-8719 (doi:10.1021/acssuschemeng.7b01483)
The building blocks for high performance in electrocatalytic CO₂ reduction: materials, optimization strategies, and device engineering
G.O. Larrazábal, A.J. Martín, J. Pérez-Ramírez
J. Phys. Chem. Lett. 2017, 8, 3933-3944 (doi:10.1021/acs.jpclett.7b01380)
Olefins from natural gas via oxychlorination
G. Zichittella, N. Aellen, V. Paunović, A.P. Amrute, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2017, 56, 13670-13674 (doi:10.1002/anie.201706624, hot paper, inside back cover, highlighted in Chimia)
Angew. Chem. 2017, 129, 13858-13862 (doi:10.1002/ange.201706624)
Mechanism of ethylene oxychlorination over ruthenium oxide
M.D. Higham, M. Scharfe, M. Capdevila-Cortada, J. Pérez-Ramírez, N. López
J. Catal. 2017, 353, 171-180 (doi:10.1016/j.jcat.2017.07.013)
Semi-hydrogenation of acetylene on indium oxide: proposed single ensemble catalysis
D. Albani, M. Capdevila-Cortada, G. Vilé, S. Mitchell, O. Martin, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2017, 56, 10755-10760 (doi:10.1002/anie.201704999)
Angew. Chem. 2017, 129, 10895-10900 (doi:10.1002/ange.201704999)
Tailoring the framework composition of carbon nitride to improve the catalytic efficiency of the stabilised palladium atoms
E. Vorobyeva, Z. Chen, S. Mitchell, R. K. Leary, P. Midgley, J. M. Thomas, R. Hauert, E. Fako, N. López, J. Pérez-Ramírez
J. Mater. Chem. A 2017, 5, 16393-16403 (doi:10.1039/C7TA04607C, featured in a themed collection of International Year of the Periodic Table : Single Atoms as Active Catalysts)
Visualising compositional heterogeneity during the scale up of multicomponent zeolite bodies
A.J. Martin, S. Mitchell, K. Kunze, K.C. Weston, J. Pérez-Ramírez
Mater. Horiz. 2017, 4, 857-861 (doi:10.1039/C7MH00088J, inside front cover)
Europium oxybromide catalysts for efficient bromine looping in natural gas valorization
V. Paunović, R. Lin, M. Scharfe, A.P. Amrute, S. Mitchell, R. Hauert, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2017, 56, 9791-9795 (doi:10.1002/anie.201704406)
Angew. Chem. 2017, 129, 9923-9927 (doi:10.1002/ange.201704406)
Operando spectroscopy of the gas-phase aldol condensation of propanal over solid base catalysts
A.M. Hernández-Giménez, J. Ruiz-Martínez, B. Puértolas, J. Pérez-Ramírez, P.C.A. Bruijnincx, B.M. Weckhuysen
Top. Catal. 2017, 60, 1522-1536 (doi:10.1007/s11244-017-0836-7)
Design of a technical Mg-Al mixed oxide catalyst for the continuous manufacture of glycerol carbonate
G.M. Lari, A.B.L. de Moura, L. Weimann, S. Mitchell, C. Mondelli, J. Pérez-Ramírez
J. Mater. Chem. A 2017, 5, 16200-16211 (doi:10.1039/C7TA02061A)
Mapping the birth and evolution of pores upon thermal activation of layered hydroxides
R. Warringham, S. Mitchell, R. Murty, R. Schaeublin, P. Crivelli, J. Kenvin, J. Pérez-Ramírez
Chem. Mater. 2017, 29, 4052-4062 (doi:10.1021/acs.chemmater.7b00734, front cover)
On the influence of Si:Al ratio and hierarchical porosity of FAU zeolites in solid acid catalysed esterification pretreatment of bio-oil
A. Osatiashtiani, B. Puértolas, C. Olivera, J.C. Manayil, B. Barbero, M. Isaacs, J. Pérez-Ramírez, E. Heracleous, A.F. Lee, K. Wilson
Biomass Convers. Biorefin. 2017, 7, 331-342 (doi:10.1007/s13399-017-0254-x)
Advanced kinetic models through mechanistic understanding: population balances for methylenedianiline synthesis
M.O. Haus, T.C. Keller, J. Arras, J. Pérez-Ramírez
Chem. Eng. Sci. 2017, 167, 317-326 (doi:10.1016/j.ces.2017.02.008)
Catalytic oxychlorination versus oxybromination for methane functionalization
G. Zichittella, V. Paunović, A.P. Amrute, J. Pérez-Ramírez
ACS Catal. 2017, 7, 1805-1817 (doi:10.1021/acscatal.6b03600)
Halogen-mediated conversion of hydrocarbons to commodities
R. Lin, A.P. Amrute, J. Pérez-Ramírez
Chem. Rev. 2017, 117, 4185-4247 (doi:10.1021/acs.chemrev.6b00551, front cover)
Bifunctional hierarchical zeolite-supported silver catalysts for the conversion of glycerol to allyl alcohol
G.M. Lari, Z. Chen, C. Mondelli, J. Pérez-Ramírez
ChemCatChem 2017, 9, 2195–2202 (doi:10.1002/cctc.201601635)
Status and prospects in higher alcohols synthesis from syngas
H.T. Luk, C. Mondelli, D. Curulla-Ferré, J.A. Stewart, J. Pérez-Ramírez
Chem. Soc. Rev. 2017, 46, 1358-1426 (doi:10.1039/c6cs00324a, inside front cover)
Pore topology effects in positron annihilation spectroscopy of zeolites
A. Zubiaga, R. Warringham, S. Mitchell, L. Gerchow, D. Cooke, P. Crivelli, J. Pérez-Ramírez
ChemPhysChem 2017, 18, 470-479 (doi:10.1002/cphc.201601258, front cover)
Stabilization of single metal atoms on graphitic carbon nitride
Z. Chen, S. Mitchell, E. Vorobyeva, R.K. Leary, R. Hauert, T. Furnival, Q.M. Ramasse, J.M. Thomas, P.A. Midgley, D. Dontsova, M. Antonietti, S. Pogodin, N. López, J. Pérez-Ramírez
Adv. Funct. Mater. 2017, 27, 1605785 (doi:10.1002/adfm.201605785, frontispiece)
Solvothermally-prepared Cu₂O electrocatalysts for CO₂ reduction with tunable selectivity by the introduction of p-block elements
G.O. Larrazábal, A.J. Martín, F. Krumeich, R. Hauert, J. Pérez-Ramírez
ChemSusChem 2017, 10, 1255-1265 (doi:10.1002/cssc.201601578)
Hybrid palladium nanoparticles for direct H₂O₂ synthesis: the key role of the ligand
G.M. Lari, B. Puértolas, M. Shahrokhi, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2017, 56, 1775-1779 (doi:10.1002/anie.201610552, hot paper, front cover)
Angew. Chem. 2017, 129, 1801-1805 (doi:10.1002/ange.201610552)
Interfacial acidity in ligand-modified ruthenium nanoparticles boosts the performance for the continuous hydrogenation of levulinic acid to gamma-valerolactone
D. Albani, Q. Li, G. Vilé, S. Mitchell, N. Almora-Barrios, P.T. Witte, N. López, J. Pérez-Ramírez
Green Chem. 2017, 19, 2361-2370 (doi:10.1039/C6GC02586B, front cover)
Engineering of ZSM-5 zeolite crystals for enhanced lifetime in the production of light olefins via 2-methyl-2-butene cracking
S. Mitchell, M. Boltz, J. Liu, J. Pérez-Ramírez
Catal. Sci. Technol. 2017, 7, 64-74 (doi:10.1039/C6CY01009A, inside front cover, highlighted article, hot article)
Electrochemical effects at surfactant-Pt nanoparticle interfaces boost catalytic performance
N. Almora-Barrios, G. Vilé, M. García-Ratés, J. Pérez-Ramírez, N. López
ChemCatChem 2017, 9, 604-609 (doi:10.1002/cctc.201601134)
Platform chemicals via zeolite-catalyzed fast pyrolysis of glucose
B. Puértolas, Q. Imtiaz, C.R. Müller, J. Pérez-Ramírez
ChemCatChem 2017, 9, 1579-1582 (doi:10.1002/cctc.201601052)
Selective production of carbon monoxide via methane oxychlorination over vanadyl pyrophosphate
V. Paunović, G. Zichittella, R. Verel, A.P. Amrute, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2016, 55, 15619-15623 (doi:10.1002/anie.201608165, hot paper, inside back cover, highlighted twice [1, 2] in Chemistry Views)
Angew. Chem. 2016, 128, 15848-15852 (doi:10.1002/ange.201608165)
Lanthanide compounds as catalysts for the one-step synthesis of vinyl chloride from ethylene
M. Scharfe, P.A. Lira-Parada, A.P. Amrute, S. Mitchell, J. Pérez-Ramírez
J. Catal. 2016, 344, 524-534 (doi:10.1016/j.jcat.2016.10.026)
Insights into the mechanism of zeolite detemplation by positron annihilation lifetime spectroscopy
R. Warringham, L. Gerchow, A. Zubiaga, D. Cooke, P. Crivelli, S. Mitchell, J. Pérez-Ramírez
J. Phys. Chem. C 2016, 120, 25451-25461 (doi:10.1021/acs.jpcc.6b08931)
Catalyst and process design for the continuous manufacture of rare sugar alcohols by epimerization-hydrogenation of aldoses
G.M. Lari, O.G. Gröninger, Q. Li, C. Mondelli, N. López, J. Pérez-Ramírez
ChemSusChem 2016, 9, 3407-3418 (doi:10.1002/cssc.201600755, front cover)
Synthesis-property-performance relationships of amorphous silica-alumina catalysts for the production of methylenedianiline and higher homologues
T.C. Keller, J. Arras, M.O. Haus, R. Hauert, A. Kenvin, J. Kenvin, J. Pérez-Ramírez
J. Catal. 2016, 344, 757-767 (doi:10.1016/j.jcat.2016.08.016)
Enhanced reduction of CO₂ to CO over Cu-In electrocatalysts: catalyst evolution is the key
G.O. Larrazábal, A.J. Martín, S. Mitchell, R. Hauert, J. Pérez-Ramírez
ACS Catal. 2016, 6, 6265-6274 (doi:10.1021/acscatal.6b02067)
Structuring hybrid palladium nanoparticles in metallic monolithic reactors for continuous-flow three-phase alkyne hydrogenation
D. Albani, G. Vilé, M.A. Beltran Toro, R. Kaufmann, S. Mitchell, J. Pérez-Ramírez
React. Chem. Eng. 2016, 1, 454-462 (doi:10.1039/c6re00114a)
Operando synchrotron X-ray powder diffraction and modulated-excitation infrared spectroscopy elucidate the CO₂ promotion on a commercial methanol synthesis catalyst
O. Martin, C. Mondelli, A. Cervellino, D. Ferri, D. Curulla-Ferré, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2016, 55, 11031-11036 (doi:10.1002/anie.201603204)
Angew. Chem. 2016, 128, 11197-11202 (doi:10.1002/ange.201603204)
Mechanochemically activated CaO-based MgO-stabilized CO₂ sorbents: Highly effective materials prepared via a scalable technique
A. Kurlov, M. Broda, D. Hosseini, S. Mitchell, J. Pérez-Ramírez, C.R. Müller
ChemSusChem 2016, 9, 2380-2390 (doi:10.1002/cssc.201600510)
Glycerol oxidehydration to pyruvaldehyde over silver-based catalysts for improved lactic acid production
G.M. Lari, R. García-Muelas, C. Mondelli, N. López, J. Pérez-Ramírez
Green Chem. 2016, 18, 4682-4692 (doi:10.1039/C6GC00894A)
Structural analysis of IPC zeolites and related materials using positron annihilation spectroscopy and high-resolution argon adsorption
J. Jagiello, M. Sterling, P. Eliášová, M. Opanasenko, A. Zukal, R.E. Morris, M. Navaro, Alvaro Mayoral, P. Crivelli, R. Warringham, S. Mitchell, J. Pérez-Ramírez, J. Čejka
Phys. Chem. Chem. Phys. 2016, 18, 15269-15277 (doi:10.1039/c6cp01950a)
Quantifying the complex pore architecture of hierarchical faujasite zeolites and the impact on diffusion
J. Kenvin, S. Mitchell, M. Sterling, R. Warringham, T. C. Keller, P. Crivelli, J. Jagiello, J. Pérez-Ramírez
Adv. Funct. Mater. 2016, 26, 5621-5630 (doi:10.1002/adfm.201601748)
Catalyst design for natural gas upgrading via oxybromination chemistry
V. Paunović, G. Zichittella, M. Moser, A.P. Amrute, J. Pérez-Ramírez
Nat. Chem. 2016, 8, 803-809 (doi:10.1038/nchem.2522)
Phase-controlled synthesis of iron phosphates via phosphation of β-FeOOH nanorods
R. Lin, A.P. Amrute, F. Krumeich, K. Lázár, R. Hauert, M. Yulikov, J. Pérez-Ramírez
CrystEngComm 2016, 18, 3174-3185 (doi:10.1039/C6CE00501B, front cover)
The assessment of pore connectivity in hierarchical zeolites using positron annihilation lifetime spectroscopy: instrumental and morphological aspects
A. Zubiaga, R. Warringham, M. Boltz, D. Cooke, P. Crivelli, D. Gidley, J. Pérez-Ramírez, S. Mitchell
Phys. Chem. Chem. Phys. 2016, 18, 9211-9219 (doi:10.1039/C6CP00408C)
Indium oxide as a superior catalyst for methanol synthesis via CO₂ hydrogenation
O. Martin, A.J. Martín, C. Mondelli, S. Mitchell, T.F. Segawa, R. Hauert, C. Drouilly, D. Curulla-Ferré, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2016, 55, 6261-6265 (doi:10.1002/anie.201600943, front cover, highlighted in C&EN)
Angew. Chem. 2016, 128, 6369-6373 (doi:10.1002/ange.201600943)
Hierarchical NaY zeolites for lactic acid dehydration to acrylic acid
G.M. Lari, B. Puértolas, M.S. Frei, C. Mondelli, J. Pérez-Ramírez
ChemCatChem 2016, 8, 1507-1514 (doi:10.1002/cctc.201600102, inside back cover, highlighted in Chemistry Views)
Reactivity descriptors for ceria in catalysis
M. Capdevila-Cortada, G. Vilé, D. Teschner, J. Pérez-Ramírez, N. López
Appl. Catal., B 2016, 197, 299-312 (doi:10.1016/j.apcatb.2016.02.035)
Impact of daily startup-shutdown conditions on the production of solar methanol over a commercial Cu-ZnO-Al₂O₃ catalyst
U. Ash-Kurlander, O. Martin, L. D. Fontana, V. R. Patil, M. Bernegger, C. Mondelli, J. Pérez-Ramírez, A. Steinfeld
Energy Technol. 2016, 4, 565-572 (doi:10.1002/ente.201600022, front cover, highlighted in Chemistry Views)
Understanding the structure of cationic sites in alkali metal-grafted USY zeolites
T.C. Keller, M. Položij, B. Puértolas, H.V. Thang, P. Nachtigall, J. Pérez-Ramírez
J. Phys. Chem. C 2016, 120, 4954-4960 (doi:10.1021/acs.jpcc.5b12413)
Merging single atom dispersed silver and carbon nitride to a joint electronic system via co-polymerization with silver tricyanomethanide
Z. Chen, S. Pronkin, T. Fellinger, K. Kailasam, G. Vilé, D. Albani, F.Krumeich, R. Leary, J. Barnard, J.M. Thomas, J. Pérez-Ramírez, M.Antonietti, D. Dontsova
ACS Nano 2016, 10, 3166-3175 (doi:10.1021/acsnano.5b04210)
Selective dehydrogenation of bioethanol to acetaldehyde over basic USY zeolites
G.M. Lari, K. Desai, C. Mondelli, J. Pérez-Ramírez
Catal. Sci. Technol. 2016, 6, 2706-2714 (doi:10.1039/C5CY02020D)
Interplay between surface chemistry and performance on rutile-type catalysts for halogen production
M. Moser, V. Paunović, Z. Guo, L. Szentmiklósi, M.G. Hevia, M. Higham, N. López, D. Teschner, J. Pérez-Ramírez
Chem. Sci. 2016, 7, 2996-3005 (doi:10.1039/C5SC04247J, inside front cover)
Oxychlorination-dehydrochlorination chemistry on bifuctional ceria catalysts for intensified vinyl chloride production
M. Scharfe, P.A. Lira-Parada, V. Paunović, M. Moser, A.P. Amrute, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2016, 55, 3068-3072 (doi:10.1002/anie.201510903)
Angew. Chem. 2016, 128, 3120-3124 (doi:10.1002/ange.201510903)
Synergistic effects in silver-indium electrocatalysts for carbon dioxide reduction
G.O. Larrazábal, A.J. Martín, S. Mitchell, R. Hauert, J. Pérez-Ramírez
J. Catal. 2016, 343, 266-277 (doi:10.1016/j.jcat.2015.12.014)
Advances in the design of nanostructured catalysts for selective hydrogenation
G. Vilé, D. Albani, N. Almora-Barrios, N. López, J. Pérez-Ramírez
ChemCatChem 2016, 8, 21-23 (doi:10.1002/cctc.201501269)
Ligand ordering determines the catalytic response of hybrid palladium nanoparticles in hydrogenation
D. Albani, G. Vilé, S. Mitchell, P.T. Witte, N. Almora-Barrios, R. Verel, N. López, J. Pérez-Ramírez
Catal. Sci. Technol. 2016, 6, 1621-1631 (doi:10.1039/C5CY01921D)
Alkaline-assisted stannation of beta zeolite as a scalable route to Lewis-acid catalysts for the valorisation of renewables
P.Y. Dapsens, C. Mondelli, J. Pérez-Ramírez
New. J. Chem. 2016, 40, 4136-4139 (doi:10.1039/C5NJ01834J)
Environmental and economic assessment of glycerol oxidation to dihydroxyacetone over technical iron zeolite catalysts
G.M. Lari, C. Mondelli, S. Papadokonstantakis, M. Morales, K. Hungerbühler, J. Pérez-Ramírez
React. Chem. Eng. 2016, 1, 106-118 (doi:10.1039/c5re00090d)
Deoxygenation of bio-oil over solid base catalysts: From model to realistic feeds
B. Puértolas, T. Keller, S. Mitchell, J. Pérez-Ramírez
Appl. Catal., B 2016, 184, 77-86 (doi:10.1016/j.apcatb.2015.11.017)
Deactivation mechanisms of tin-zeolites in biomass conversions
G.M. Lari, P.Y. Dapsens, D. Scholz, S. Mitchell, C. Mondelli, J. Pérez-Ramírez
Green Chem. 2016, 18, 1249-1260 (doi:10.1039/C5GC02147B, inside front cover, highlighted in Chemistry World)
Synthesis, characterisation, and catalytic evaluation of hierarchical faujasite zeolites: milestones, challenges, and future directions
D. Verboekend, N. Nuttens, R. Locus, P. Verolme, J.C. Groen, J. Pérez-Ramírez, B.F. Sels
Chem. Soc. Rev. 2016, 45, 3331-3352 (doi:10.1039/c5cs00520e, front cover)
Immobilizing and de-immobilizing enzymes on mesoporous silica
V. Zlateski, T.C. Keller, J. Pérez-Ramírez, R.N. Grass
RSC Adv. 2015, 5, 87706-87712 (doi:10.1039/C5RA19568C)
Towards sustainable fuels and chemicals through the electrochemical reduction of CO₂: lessons from water electrolysis
A.J. Martín, G.O. Larrazábal, J. Pérez-Ramírez
Green Chem. 2015, 17, 5114-5130 (doi:10.1039/C5GC01893E, front cover)
Design of Lewis-acid centres in zeolitic matrices for the conversion of renewables
P.Y. Dapsens, C. Mondelli, J. Pérez-Ramírez
Chem. Soc. Rev. 2015, 44, 7025-7043 (doi:10.1039/c5cs00028a, front cover)
Structural analysis of hierarchically-organized zeolites
S. Mitchell, A.B. Pinar, J. Kenvin, P. Crivelli, J. Kärger, J. Pérez-Ramírez
Nat. Commun. 2015, 6:8633 (doi:10.1038/ncomms9633)
Aluminum redistribution during the preparation of hierarchical zeolites by desilication
S. Mitchell, M. Milina, R. Verel, M. Hernández-Rodríguez, A.B. Pinar, L.B. McCusker, J. Pérez-Ramírez
Chem. Eur. J. 2015, 21, 14156-14164 (doi:10.1002/chem.201500992)
Structure and reactivity of ceria-zirconia catalysts for bromine and chlorine production via the gas-phase oxidation of hydrogen halides
M. Moser, G. Vilé, S. Colussi, F. Krumeich, D. Teschner, L. Szentmiklósi, A. Trovarelli, J. Pérez-Ramírez
J. Catal. 2015, 331, 128-137 (doi:10.1016/j.jcat.2015.08.024)
Zinc-rich copper catalysts promoted by gold for methanol synthesis
O. Martin, C. Mondelli, D. Curulla-Ferré, C. Drouilly, R. Hauert, J. Pérez-Ramírez
ACS Catal. 2015, 5, 5607-5616 (doi:10.1021/acscatal.5b00877)
Design of base zeolite catalysts by alkali-metal grafting in alcoholic media
T.C. Keller, K. Desai, S. Mitchell, J. Pérez-Ramírez
ACS Catal. 2015, 5, 5388-5396 (doi:10.1021/acscatal.5b00761)
Structure and reactivity of supported hybrid platinum nanoparticles for the flow hydrogenation of functionalized nitroaromatics
G. Vilé, N. Almora-Barrios, N. López, J. Pérez-Ramírez
ACS Catal. 2015, 5, 3767-3778 (doi:10.1021/acscatal.5b00885)
Structure analysis of a BEC-type germanosilicate zeolite including the location of the flexible organic cations in the channels
S. Smeets, L. Koch, N. Mascello, J. Sesseg, L.B. McCusker, M. Hernández-Rodríguez, S. Mitchell, J. Pérez-Ramírez
CrystEngComm 2015, 17, 4865-4870 (doi:10.1039/C5CE00731C)
Porosity-acidity interplay in hierarchical ZSM-5 zeolites for pyrolysis oil valorization to aromatics
B. Puértolas, A. Veses, M.S. Callén, S. Mitchell, T. García, J. Pérez-Ramírez
ChemSusChem 2015, 12, 2383-3293 (doi:10.1002/cssc.201500685)
Hierarchically-structured MnO₂-Co/C nanocomposites: highly efficient and magnetically-recyclable catalysts for the aerobic oxidation of alcohols
J. Zhi, S. Mitchell, J. Pérez-Ramírez, O. Reiser
ChemCatChem 2015, 7, 2585-2589 (doi:10.1002/cctc.201500549)
A stable single-site palladium catalyst for hydrogenations
G. Vilé, D. Albani, M. Nachtegaal, Z. Chen, D. Dontsova, M. Antonietti, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2015, 54, 11265-11269 (doi:10.1002/anie.201505073, front cover, highlighted in Nature and in C&EN)
Angew. Chem. 2015, 127, 11417-11422 (doi:10.1002/ange.201505073, front cover, highlighted in Nature and in C&EN )
Hemicellulose arabinogalactan hydrolytic hydrogenation over Ru-modified H-USY zeolites
D. Yu. Murzin, B. Kusema, E.V. Murzina, A. Aho, A. Tokarev, A.S. Boymirzaev, J. Wärnå, P.Y. Dapsens, C. Mondelli, J. Pérez-Ramírez, T. Salmi
J. Catal. 2015, 330, 93-105 (doi:10.1016/j.jcat.2015.06.022)
Continuous transfer hydrogenation of sugars to alditols with bio-derived donors over Cu-Ni-Al catalysts
D. Scholz, C. Aellig, C. Mondelli, J. Pérez-Ramírez
ChemCatChem 2015, 7, 1551-1558 (doi:10.1002/cctc.201403005, front cover)
When catalyst meets reactor: continuous biphasic processing of xylan to furfural over GaUSY/Amberlyst-36
C. Aellig, D. Scholz, P.Y. Dapsens, C. Mondelli, J. Pérez-Ramírez
Catal. Sci. Technol. 2015, 5, 142-149 (doi:10.1039/C4CY00973H, front cover)
Gas-phase oxidation of glycerol to dihydroxyacetone over tailored iron zeolites
G.M. Lari, C. Mondelli, J. Pérez-Ramírez
ACS Catal. 2015, 5, 1453-1461 (doi:10.1021/cs5019056)
Unified method to the total pore volume and pore size distribution of hierarchical zeolites from argon adsorption and mercury intrusion
J. Kenvin, J. Jagiello, S. Mitchell, J. Pérez-Ramírez
Langmuir 2015, 31, 1242-1247 (doi:10.1021/la504575s)
Structuring zeolite bodies for enhanced heat-transfer properties
L. Borchardt, N.-L. Michels, T. Nowak, S. Mitchell, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2015, 208, 196-202 (doi:10.1016/j.micromeso.2015.01.028)
Environmental and economic assessment of lactic acid production from glycerol using cascade bio- and chemocatalysis
M. Morales, P.Y. Dapsens, I. Giovinazzo, J. Witte, C. Mondelli, S. Papadokonstantakis, K. Hungerbühler, J. Pérez-Ramírez
Energy Environ. Sci. 2015, 8, 558-567 (doi:10.1039/c4ee03352c)
Impact of pore connectivity in the design of long-lived zeolite catalysts
M. Milina, S. Mitchell, D. Cooke, P. Crivelli, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2015, 54, 1591-1594 (doi:10.1002/anie.201410016, back cover)
Angew. Chem. 2015, 127, 1698-1701 (doi:10.1002/ange.201411639, back cover)
Design of hierarchical zeolite catalysts for the manufacture of polyurethane intermediates
T.C. Keller, J. Arras, S. Wershofen, J. Pérez-Ramírez
ACS Catal. 2015, 5, 734-743 (doi:10.1021/cs5017694)
Impact of feed impurities on catalysts for chlorine recycling
M. Moser, A.P. Amrute, J. Pérez-Ramírez
Appl. Catal., B 2015, 162, 602-609 (doi:10.1016/j.apcatb.2014.07.037)
Hydroxyapatite, an exceptional catalyst for the gas-phase deoxygenation of bio-oil by aldol condensation
E.G. Rodrigues, T.C. Keller, S. Mitchell, J. Pérez-Ramírez
Green Chem. 2014, 16, 4870-4874 (doi:10.1039/C4GC01432D, front cover)
Opposite face sensitivity of CeO₂ in hydrogenation and oxidation catalysis
G. Vilé, S. Colussi, F. Krumeich, A. Trovarelli, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2014, 53, 12069-12072 (doi:10.1002/anie.201406637, front cover)
Angew. Chem. 2014, 126, 12265-12268
Design of hydrothermally-stable dawsonite-based sorbents in technical form for CO₂ capture
O. Martin, M. Hammes, S. Mitchell, J. Pérez-Ramírez
Energy Envion. Sci. 2014, 7, 3640-3650 (doi:10.1039/c4ee02012j)
Silver nanoparticles supported on passivated silica: preparation and catalytic performance in alkyne semi-hydrogenation
E. Oakton, G. Vilé, D. Levine, E. Zocher, D. Baudouin, J. Pérez-Ramírez, C. Copéret
Dalton Trans. 2014, 43, 15138-15142 (doi:10.1039/C4DT01320D)
Beyond the use of modifiers in selective alkyne hydrogenation: silver and gold nanocatalysts in flow mode for sustainable alkene production
G. Vilé, J. Pérez-Ramírez
Nanoscale 2014, 6, 13476-13482 (doi:10.1039/C4NR02777A, front cover)
Hierarchical silicoaluminophosphates by post-synthetic modification: influence of topology, composition, and silicon distribution
D. Verboekend, M. Milina, J. Pérez-Ramírez
Chem. Mater. 2014, 26, 4552-4562 (doi:10.1021/cm501774s)
Effects of binders on the performance of shaped hierarchical MFI zeolites in methanol-to-hydrocarbons
N.-L. Michels, S. Mitchell, J. Pérez-Ramírez
ACS Catal. 2014, 4, 2409-2417 (doi:10.1021/cs500353b, front cover)
Stereo- and Chemoselective Character of Supported CeO₂ Catalysts for Continuous-Flow Three-Phase Alkyne Hydrogenation
G. Vilé, S. Wrabetz, L. Floryan, M.E. Schuster, F. Girgsdies, D. Teschner, J. Pérez-Ramírez
ChemCatChem 2014, 6, 1928-1934 (doi:10.1002/cctc.201402124)
Generation of novel basic centers in high-silica zeolites and their application in the gas-phase upgrading of bio-oil
T.C. Keller, E.G. Rodrigues, J. Pérez-Ramírez
ChemSusChem 2014, 7, 1729-1738 (doi:10.1002/cssc.201301382)
From the Lindlar catalyst to supported ligand-modified palladium nanoparticles: selectivity patterns and accessibility constraints in the continuous-flow three-phase hydrogenation of acetylenic compounds
G. Vilé, N. Almora-Barrios, S. Mitchell, N. López, J. Pérez-Ramírez
Chem. Eur. J. 2014, 20, 5926-5937 (doi:10.1002/chem.201304795, front cover, highlighted in ChemistryViews)
Superior mass transfer properties of technical zeolite bodies with hierarchical porosity
L. Gueudré, M. Milina, S. Mitchell, J. Pérez-Ramírez
Adv. Funct. Mater. 2014, 24, 209-219 (doi:10.1002/adfm.201203557, inside cover)
Mesopore quality determines the lifetime of hierarchically-structured zeolite catalysts
M. Milina, S. Mitchell, P. Crivelli, D. Cooke, J. Pérez-Ramírez
Nat. Commun. 2014, 5:3922 (doi:10.1038/ncomms4922)
Rediscovering zeolite mechanochemistry - a pathway beyond current synthesis and modification boundaries
G. Majano, L. Borchardt, S. Mitchell, V. Valtchev, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2014, 194, 106-114 (doi:10.1016/j.micromeso.2014.04.006)
Hierarchical Sn-MFI zeolites prepared by facile top-down methods for sugar isomerization
P.Y. Dapsens, C. Mondelli, J. Jagielski, R. Hauert, J. Pérez-Ramirez
Catal. Sci. Technol. 2014, 4, 2302-2311 (doi:10.1039/C4CY00172A)
The virtue of defects: stable bromine production via catalytic oxidation of hydrogen bromide on titanium oxide
M. Moser, I. Czekaj, N. López, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2014, 53, 8628-8633 (doi:10.1002/anie.201404022, frontispiece)
Angew. Chem. 2014, 126, 8872-8777 (doi: 10.1002/ange.201404022, frontispiece)
Prospectives for bio-oil upgrading via esterification over zeolite catalysts
M. Milina, S. Mitchell, J. Pérez-Ramírez
Catal. Today 2014, 235, 176-183 (doi:10.1016/j.cattod.2014.02.047)
Solvent-mediated reconstruction of the metal-organic framework HKUST-1 (Cu₃(BTC)₂)
G. Majano, O. Martin, M. Hammes, S. Smeets, C. Baerlocher, J. Pérez-Ramírez
Adv. Funct. Mater. 2014, 24, 3855-3865 (doi:10.1002/adfm.201303678, VIP paper, front cover)
Towards a sustainable manufacture of hierarchical zeolites
D. Verboekend, J. Pérez-Ramírez
ChemSusChem 2014, 7, 753-764 (doi:10.1002/cssc.201301313, front cover)
Bifunctional Cu/H-ZSM-5 zeolite with hierarchical porosity for hydrocarbon abatement under cold-start conditions
B. Puértolas, L. García-Andujar, T. García, M.V. Navarro, S. Mitchell, J. Pérez-Ramírez
Appl. Catal., B 2014, 154-155, 161-170 (doi:10.1016/j.apcatb.2014.02.013)
Molecular-level understanding of CeO₂ as a catalyst for partial alkyne hydrogenation
J. Carrasco, G. Vilé, D. Fernández-Torre, R. Pérez, J. Pérez-Ramírez, M.V. Ganduglia-Pirovano
J. Phys. Chem. C 2014, 118, 5352-5360 (doi:10.1021/jp410478c, front cover)
Catalyst distribution strategies in fixed-bed reactors for bromine production
M. Moser, L. Rodríguez-García, J. Pérez-Ramírez
Ind. Eng. Chem. Res. 2014, 53, 9067-9075 (doi:10.1021/ie4036675)
A continuous process for glyoxal valorisation using tailored lewis-acid zeolite catalysts
P.Y. Dapsens, C. Mondelli, B. Kusema, R. Verel, J. Pérez-Ramírez
Green Chem. 2014, 16, 1176-1186 (doi:10.1039/C3GC42353K, hot article, front cover)
Palladium nanoparticles supported on magnetic carbon‐coated cobalt nanobeads: Highly active and recyclable catalysts for alkene hydrogenation
Q.M. Kainz, R. Linhardt, R. Grass, G. Vilé, J. Pérez-Ramírez, W.J. Stark, O. Reiser
Adv. Funct. Mater. 2014, 24, 2020-2027 (doi:10.1002/adfm.201303277)
Structural changes of a U₃O₈/ZrO₂ catalyst during HCl oxidation - a HAADF-STEM study
F. Krumeich, A.P. Amrute, C. Mondelli, J. Pérez-Ramírez
Z. Anorg. Allg. Chem. 2014, 640, 768-773 (doi:10.1002/zaac.201300490)
Hierarchical high-silica zeolites as superior base catalysts
T.C. Keller, S. Isabettini, D. Verboekend, E.G. Rodrigues, J. Pérez-Ramírez
Chem. Sci. 2014, 5, 677-684 (doi:10.1039/C3SC51937F)
Gallium-modified zeolites for the selective conversion of bio-based dihydroxyacetone into C1-C4 alkyl lactates
P.Y. Dapsens, B.T. Kusema, C. Mondelli, J. Pérez-Ramírez
J. Mol. Catal. A, Chem. 2014, 388-389, 141-147 (doi:10.1016/j.molcata.2013.09.032)
Production of bio-derived ethyl lactate on GaUSY zeolites prepared by post-synthetic galliation
P.Y. Dapsens, M. Menart, C. Mondelli, J. Pérez-Ramírez
Green Chem. 2014, 16, 589-593 (doi:10.1039/C3GC40766G)
Solid-state chemistry of cuprous delafossites: synthesis and stability aspects
A.P. Amrute, Z. Łodziana, C. Mondelli, F. Krumeich, J. Pérez-Ramírez
Chem. Mater. 2013, 25, 4423-4435 (doi:10.1021/cm402902m)
HCl oxidation on IrO₂-based catalysts: from fundamentals to scale up
M. Moser, C. Mondelli, A.P Amrute, A. Tazawa, D. Teschner, M.E. Schuster, A. Klein-Hoffman, N. López, T. Schmidt, J. Pérez-Ramírez
ACS Catal. 2013, 3, 2813-2822 (doi:10.1021/cs400553t)
New and revisited insights into the promotion of methanol synthesis catalysts by CO₂
O. Martin, J. Pérez-Ramírez
Catal. Sci. Technol. 2013, 3, 3343-3352 (doi:10.1039/C3CY00573A)
Hierarchical zeolites by desilication: occurrence and catalytic impact of recrystallization and restructuring
D. Verboekend, M. Milina, S. Mitchell, J. Pérez-Ramírez
Cryst. Growth Des. 2013, 13, 5025-5035 (doi:10.1021/cg4010483, front cover)
Silver nanoparticles for olefin production: new insights into the mechanistic description of propyne hydrogenation
G. Vilé, D. Baudouin, I.N. Remediakis, C. Copéret, N. López, J. Pérez-Ramírez
ChemCatChem 2013, 5, 3750-3759 (doi:10.1002/cctc.201300569)
Catalytic bromine recovery: an enabling technology for emerging alkane functionalization processes
M. Moser, L. Rodríguez-García, A.P. Amrute, J. Pérez-Ramírez
ChemCatChem 2013, 5, 3520-3523 (doi:10.1002/cctc.201300609)
Interdependence between porosity, acidity, and catalytic performance in hierarchical ZSM-5 zeolites prepared by post-synthetic modification
M. Milina, S. Mitchell, N.-L. Michels, J. Kenvin, J. Pérez Ramírez
J. Catal. 2013, 308, 398-407 (doi:10.1016/j.jcat.2013.08.020)
Status and perspectives of CO₂ valorisation by catalytic, photocatalytic and electrocatalytic processes
E.V. Kondratenko, G. Mul, J. Baltrusaitis, G.O. Larrazábal, J. Pérez-Ramírez
Energy Environ. Sci. 2013, 6, 3112-3135 (doi:10.1039/C3EE41272E)
Room-temperature synthesis of Fe-BTC from layered iron hydroxides: influence of precursor organisation
G. Majano, O. Ingold, M. Yulikov, G. Jeschke, J. Pérez-Ramírez
CrystEngComm 2013, 15, 9885-9892 (doi:10.1039/C3CE41366G, hot article and front cover)
Superior activity of rutile-supported ruthenium nanoparticles for HCl oxidation
E.V. Kondratenko, A.P. Amrute, M.-M. Pohl, N. Steinfeldt, C. Mondelli, J. Pérez-Ramírez
Catal. Sci. Technol. 2013, 3, 2555-2558 (doi:10.1039/C3CY00372H, hot article)
CuCrO₂ delafossite: a stable copper catalyst for Cl₂ production
A.P. Amrute, G.O. Larrazábal, C. Mondelli, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2013, 52, 9772-9775 (doi:10.1002/anie.201304254, front cover)
Angew. Chem. 2013, 125, 9954-9957 (doi:10.1002/ange.201304254, front cover)
Towards liquid fuels from biosyngas on hierarchical zeolite supported cobalt catalysts: effect of zeolite structure
S. Sartipi, M. Alberts, M.J. Meijerink, T.C. Keller, J. Pérez-Ramírez, J. Gascon, F. Kapteijn
ChemSusChem 2013, 6, 1646-1650 (doi:10.1002/cssc.201300339)
Advanced visualization strategies bridge the multidimensional complexity of technical catalysts
S. Mitchell, N.-L. Michels, G. Majano, J. Pérez-Ramírez
Curr. Opin. Chem. Eng. 2013, 2, 304-311 (doi:10.1016/j.coche.2013.04.005)
From powder to technical body: the undervalued science of catalyst scale up
S. Mitchell, N.-L. Michels, J. Pérez-Ramírez
Chem. Soc. Rev. 2013, 42, 6094-6112 (doi:10.1039/C3CS60076A, inside cover)
Hierarchical zeolites overcome all obstacles: next stop industrial implementation
D. Verboekend, S. Mitchell, J. Pérez-Ramírez
Chimia 2013, 67, 327-332 (doi:10.2533/chimia.2013.327)
Hierarchy brings function: mesoporous clinoptilolite and L zeolite catalysts synthesized by tandem acid-base treatments
D. Verboekend, T. Keller, M. Milina, R. Hauert, J. Pérez-Ramírez
Chem. Mater. 2013, 25, 1947-1959 (doi:10.1021/cm4006103, front cover)
Highly selective Lewis acid sites in desilicated MFI zeolites for dihydroxyacetone isomerization to lactic acid
P.Y. Dapsens, C. Mondelli, J. Pérez-Ramírez
ChemSusChem 2013, 6, 831-839 (doi:10.1002/cssc.201200703)
Hydroisomerization and hydrocracking of linear and multibranched long model alkanes on hierarchical Pt/ZSM-22 zeolite
J.A. Martens, D. Verboekend, K. Thomas, G. Vanbutsele, J. Pérez-Ramírez, J.-P. Gilson
Catal. Today 2013, 218-219, 135-142 (doi:10.1016/j.cattod.2013.03.041)
Industrial RuO₂-based Deacon catalysts: carrier stabilization and active phase content optimization
A.P. Amrute, C. Mondelli, T. Schmidt, R. Hauert, J. Pérez-Ramírez
ChemCatChem 2013, 5, 748-756 (doi:10.1002/cctc.201200704, back cover)
Depleted uranium catalysts for chlorine production
A.P. Amrute, F. Krumeich, C. Mondelli, J. Pérez-Ramírez
Chem. Sci. 2013, 4, 2209-2217 (doi:10.1039/C3SC22067B)
Hydroisomerization of emerging renewable hydrocarbons using hierarchical Pt/H-ZSM-22 catalyst
J.A. Martens, D. Verboekend, K. Thomas, G. Vanbutsele, J.-P. Gilson, J. Pérez-Ramírez
ChemSusChem 2013, 6, 421-425 (doi:10.1002/cssc.201200888)
Tailored crystalline microporous materials by post-synthesis modification
V. Valtchev, G. Majano, S. Mintova, J. Pérez-Ramírez
Chem. Soc. Rev. 2013, 42, 263-290 (doi:10.1039/c2cs35196j)
Understanding CeO₂ as Deacon catalyst by probe molecule adsorption and in situ infrared characterisations
R. Farra, S. Wrabetz, M.E. Schuster, E. Stotz, N.G. Hamilton, A.P. Amrute, J. Pérez-Ramírez, N. López, D. Teschner
Phys. Chem. Chem. Phys. 2013, 15, 3454-3465 (doi:10.1039/c2cp42767b)
Stabilized hierarchical USY zeolite catalysts for simultaneous increase in diesel and LPG olefinicity during catalytic cracking
C. Martínez, D. Verboekend, J. Pérez-Ramírez, A. Corma
Catal. Sci. Technol. 2013, 3, 972-981 (doi:10.1039/C2CY20688A)
Scalable room-temperature conversion of copper(II) hydroxide into HKUST-1 (Cu₃(btc)₂)
G. Majano, J. Pérez-Ramírez
Adv. Mater. 2013, 25, 1052-1057 (doi:10.1002/adma.201203664)
Supported CeO₂ catalysts in technical form for sustainable chlorine production
M. Moser, C. Mondelli, T. Schmidt, F. Girgsdies, M.E. Schuster, R. Farra, L. Szentmiklósi, D. Teschner, J. Pérez-Ramírez
Appl. Catal., B 2013, 132-133, 123-131 (doi:10.1016/j.apcatb.2012.11.024)
Hierarchical FAU and LTA-type zeolites by post-synthetic design: a new generation of highly efficient base catalysts
D. Verboekend, T.C. Keller, S. Mitchell, J. Pérez-Ramírez
Adv. Funct. Mater. 2013, 23, 1923-1934 (doi:10.1002/adfm.201202320, front cover)
Do observations on surface coverage-reactivity correlations always describe the true catalytic process? A case study on ceria
R. Farra, M. Eichelbaum, R. Schlögl, L. Szentmiklósi, T. Schmidt, A.P. Amrute, C. Mondelli, J. Pérez-Ramírez, D. Teschner
J. Catal. 2013, 297, 119-127 (doi:10.1016/j.jcat.2012.09.024)
On the location, strength and accessibility of Brønsted acid sites in hierarchical ZSM-5 particles
D. Tzoulaki, A. Jentys, J. Pérez-Ramírez, K. Egeblad, J.A. Lercher
Catal. Today 2012, 198, 3-11 (doi:10.1016/j.cattod.2012.03.078)
Room temperature synthesis and size control of HKUST-1
G. Majano, J. Pérez-Ramírez
Helv. Chim. Acta 2012, 95, 2278-2286 (doi:10.1002/hlca.201200466)
Surface and pore structure assessment of hierarchical MFI zeolites by advanced water and argon sorption studies
M. Thommes, S. Mitchell, J. Pérez-Ramírez
J. Phys. Chem. C 2012, 116, 18816-18823 (doi:10.1021/jp3051214)
Assembly of a hierarchical zeolite-silica composite by spray drying
G. Majano, A. Restuccia, M. Santiago, J. Pérez-Ramírez
CrystEngComm 2012, 14, 5985-5991 (doi:10.1039/C2CE25373A)
Kinetic aspects and deactivation behaviour of chromia-based catalysts in hydrogen chloride oxidation
A.P. Amrute, C. Mondelli, J. Pérez-Ramírez
Catal. Sci. Technol. 2012, 2, 2057-2065 (doi:10.1039/C2CY20185B)
Mechanistic study of the palladium-catalyzed ethyne hydrogenation by the Temporal Analysis of Products technique
M.A.G. Hevia, B. Bridier, J. Pérez-Ramírez
Appl. Catal. A 2012, 439-440, 163-170 (doi:10.1016/j.apcata.2012.07.001)
Biobased chemicals from conception toward industrial reality: lessons learned and to be learned
P.Y. Dapsens, C. Mondelli, J. Pérez-Ramírez
ACS Catal. 2012, 2, 1487-1499 (doi:10.1021/cs300124m)
Mesopore formation in USY and beta zeolites by base leaching: selection criteria and optimization of pore-directing agents
D. Verboekend, G. Vilé, J. Pérez-Ramírez
Cryst. Growth Des. 2012, 12, 3123-3132 (doi:10.1021/cg3003228)
Molecular understanding of enyne hydrogenation over Pd and Cu catalysts
B. Bridier, D. Karhanek, J. Pérez-Ramírez, N. López
ChemCatChem 2012, 4, 1420-1427 (doi:10.1002/cctc.201200021)
Hierarchically structured zeolite bodies: assembling micro-, meso-, and macroporosity levels in complex materials with enhanced properties
N.-L. Michels, S. Mitchell, M. Milina, K. Kunze, F. Krumeich, F. Marone, M. Erdmann, N. Marti, J. Pérez-Ramírez
Adv. Funct. Mater. 2012, 22, 2509-2518 (doi:10.1002/adfm.201103120)
By-product co-feeding reveals insights into the role of zinc on methanol synthesis catalysts
M. Santiago, K. Barbera, C. Ferreira, D. Curulla-Ferré, P. Kolb, J. Pérez-Ramírez
Catal. Commun. 2012, 21, 63-67 (doi:10.1016/j.catcom.2012.01.031)
Performance, structure, and mechanism of CeO₂ in HCl oxidation to Cl₂
A.P. Amrute, C. Mondelli, M. Moser, G. Novell-Leruth, N. López, D. Rosenthal, R. Farra, M.E. Schuster, D. Teschner, T. Schmidt, J. Pérez-Ramírez
J. Catal. 2012, 286, 287-297 (doi:10.1016/j.jcat.2011.11.016, top cited article during 2012)
Hierarchical Y and USY zeolites designed by post-synthetic strategies
D. Verboekend, G. Vilé, J. Pérez-Ramírez
Adv. Funct. Mater. 2012, 22, 916-928 (doi:10.1002/adfm.201102411, front cover)
Promotional effect of Ni in the selective gas-phase hydrogenation of chloronitrobenzene over Cu-based catalysts
F. Cárdenas-Lizana, B. Bridier, C.C. Kai Shin, J. Pérez-Ramírez, L. Kiwi-Minsker
ChemCatChem 2012, 4, 668-673 (doi:10.1002/cctc.201100470)
Influence of crystal size and probe molecule on diffusion in hierarchical ZSM-5 zeolites prepared by desilication
F.C. Meunier, D. Verboekend, J.-P. Gilson, J.C. Groen, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2012, 148, 115-121 (doi:10.1016/j.micromeso.2011.08.002)
An integrated approach to Deacon chemistry on RuO₂-based catalysts
D. Teschner, R. Farra, L. Yao, R. Schlögl, H. Soerijanto, R. Schomäcker, T. Schmidt, L. Szentmiklósi, A.P Amrute, C. Mondelli, J. Pérez-Ramírez, G. Novell-Leruth, N. López
J. Catal. 2012, 285, 273-284 (doi:10.1016/j.jcat.2011.09.039, top cited article during 2012)
Visualization of hierarchically structured zeolite bodies from macro to nano length scales
S. Mitchell, N.-L. Michels, K. Kunze, J. Pérez-Ramírez
Nature Chem. 2012, 4, 825-831 (doi:10.1038/nchem.1403)
Ceria in hydrogenation catalysis: High selectivity in the conversion of alkynes to olefins
G. Vilé, B. Bridier, J. Wichert, J. Pérez-Ramírez
Angew. Chem. Int. Ed. 2012, 51, 8620-8623 (doi:10.1002/anie.201203675, highlighted in Chimia)
Angew. Chem. 2012, 124, 8748-8751 (doi:10.1002/ange.201203675, highlighted in Chimia)
In situ surface coverage analysis of the RuO₂-catalyzed HCl oxidation reveals the entropic origin of compensation in heterogeneous catalysis
D. Teschner, G. Novell-Leruth, R. Farra, A. Knop-Gericke, R. Schlögl, L. Szentmiklósi, M. Hevia, H. Soerijanto, R. Schomäcker, J. Pérez-Ramírez, N. López
Nature Chem. 2012, 4, 739-745 (doi:10.1038/nchem.1411)
Decoupling porosity and compositional effects on desilicated ZSM-5 zeolites for optimal alkylation performance
M. Milina, S. Mitchell, Z. Domínguez Trinidad, D. Verboekend, J. Pérez-Ramírez
Catal. Sci. Technol. 2012, 2, 759-766 (doi:10.1039/C2CY00456A)
Selectivity patterns in heterogeneously catalyzed hydrogenation of conjugated ene-yne and diene compounds
B. Bridier, J. Pérez-Ramírez
J. Catal. 2011, 284, 165-175 (doi:10.1016/j.jcat.2011.10.003)
Sustainable chlorine recycling via catalysed HCl oxidation: from fundamentals to implementation
J. Pérez-Ramírez, C. Mondelli, T. Schmidt, O.F.-K. Schlüter, A. Wolf, L. Mleczko, T. Dreier
Energy Environ. Sci. 2011, 4, 4786-4799 (doi:10.1039/C1EE02190G)
Mechanistic analysis of direct N₂O decomposition and reduction with H₂ or NH₃ over RuO₂
M. Santiago, V.A. Kondratenko, E.V. Kondratenko, N. López, J. Pérez-Ramírez
Appl. Catal., B 2011, 1, 879-890 (doi:10.1016/j.apcatb.2011.08.019, front cover)
Expanding the horizons of hierarchical zeolites: beyond laboratory curiosity towards industrial realization
J. Pérez-Ramírez, S. Mitchell, D. Verboekend, M. Milina, N.-L. Michels, F. Krumeich, N. Marti, M. Erdmann
ChemCatChem 2011, 3, 1731-1734 (doi:10.1002/cctc.201100264)
Towards more efficient monodimensional zeolite catalysts: n-alkane hydro-isomerisation on hierarchical ZSM-22
D. Verboekend, K. Thomas, M. Milina, S. Mitchell, J. Pérez-Ramírez, J.-P. Gilson
Catal. Sci. Technol. 2011, 1, 1331-1335 (doi:10.1039/C1CY00240F)
Full compositional flexibility in the preparation of mesoporous MFI zeolites by desilication
D. Verboekend, S. Mitchell, M. Milina, J.C. Groen, J. Pérez-Ramírez
J. Phys. Chem. C 2011, 115, 14193-14203 (doi:10.1021/jp201671s)
Delafossite-based copper catalyst for sustainable Cl₂ production
C. Mondelli, A.P. Amrute, T. Schmidt, J. Pérez-Ramírez
Chem. Commun. 2011, 47, 7173-7175 (doi:10.1039/C1CC11891A)
Spray deposition method for the synthesis of supported catalysts with superior metal dispersion
M. Santiago, A. Restuccia, F. Gramm, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2011, 146, 76-81 (doi:10.1016/j.micromeso.2011.05.015)
Mechanism-performance relationships of metal oxides in catalyzed HCl oxidation
A.P. Amrute, C. Mondelli, M.A.G. Hevia, J. Pérez-Ramírez
ACS Catal. 2011, 1, 583-590 (doi:10.1021/cs200075j)
Surface state during activation and reaction of high-performing multi-metallic alkyne hydrogenation catalysts
B. Bridier, J. Pérez-Ramírez, A. Knop-Gericke, R. Schlögl, D. Teschner
Chem. Sci. 2011, 2, 1379-1383 (doi:10.1039/C1SC00069A)
Reevaluation of the structure and fundamental physical properties of dawsonites by DFT studies
Z. Lodziana, G. Stoica, J. Pérez-Ramírez
Inorg. Chem. 2011, 50, 2590-2598 (doi:10.1021/ic102443h)
Preparation of organic-functionalized mesoporous ZSM-5 zeolites by consecutive desilication and silanization
S. Mitchell, A. Bonilla, J. Pérez-Ramírez
Mater. Chem. Phys. 2011, 127, 278-284 (doi:10.1016/j.matchemphys.2011.02.003)
Mesoporous zeolites as enzyme carriers: synthesis, characterization, and application in biocatalysis
S. Mitchell, J. Pérez-Ramírez
Catal. Today 2011, 168, 28-37 (doi:10.1016/j.cattod.2010.10.058)
Shaped RuO₂SnO₂-Al₂O₃ catalyst for large-scale stable Cl₂ production via HCl oxidation
C. Mondelli, A.P. Amrute, F. Krumeich, T. Schmidt, J. Pérez-Ramírez
ChemCatChem 2011, 3, 657-660 (doi:10.1002/cctc.201000424, front cover, hot article)
A density functional theory study of the ‘mythic’ Lindlar hydrogenation catalyst
M. García-Mota, J. Gómez-Díaz, G. Novell-Leruth, C. Vargas, L. Bellarosa, B. Bridier, J. Pérez Ramírez, N. López
Theor. Chem. Acc. 2011, 128, 663-673 (doi:10.1007/s00214-010-0800-0)
Desilication mechanism revisited: Highly mesoporous all-silica zeolites enabled through pore-directing agents
D. Verboekend, J. Pérez-Ramírez
Chem. Eur. J. 2011, 17, 1137-1147 (doi:10.1002/chem.201002589, inside cover)
Permanent alkene selectivity enhancement in copper-catalyzed propyne hydrogenation by temporary CO supply
B. Bridier, J. Pérez-Ramírez
J. Catal. 2011, 278, 167-172 (doi:10.1016/j.jcat.2010.11.024)
Temporal analysis of products study of HCl oxidation over copper- and ruthenium-based catalysts
A.P. Amrute, C. Mondelli, M.A.G. Hevia, J. Pérez-Ramírez
J. Phys. Chem. C 2011, 115, 1056-1063 (doi:10.1021/jp1058319)
Design of hierarchical zeolite catalysts by desilication
D. Verboekend, J. Pérez-Ramírez
Catal. Sci. Technol. 2011, 1, 879-890 (doi:10.1039/C1CY00150G, front cover)
Mesoporous ZSM-22 zeolite obtained by desilication: peculiarities associated with crystal morphology and aluminium distribution
D. Verboekend, A.M. Chabaneix, K. Thomas, J.-P. Gilson, J. Pérez-Ramírez
CrystEngComm 2011, 13, 3408-3416 (doi:10.1039/C0CE00966K)
Transient mechanistic study of the gas-phase HCl oxidation to Cl₂ on bulk and supported RuO₂ catalysts
M.A.G. Hevia, A.P. Amrute, T. Schmidt, J. Pérez-Ramírez
J. Catal. 2010, 276, 141-151 (doi:10.1016/j.jcat.2010.09.009)
Stability and inter-conversion of synthetic dawsonites in aqueous media
G. Stoica, J. Pérez-Ramírez
Geochim. Cosmochim. Acta 2010, 74, 7048-7058 (doi:10.1016/j.gca.2010.09.013)
Mechanism and micro-kinetics of direct N₂O decomposition over BaFeAl₁₁O₁₉ hexaaluminate and comparison with Fe-MFI zeolites
E.V. Kondratenko, V.A. Kondratenko, M. Santiago, J. Pérez-Ramírez
Appl. Catal. B 2010, 99, 66-73 (doi:10.1016/j.apcatb.2010.05.033)
Pressure and materials effects on the selectivity of RuO₂ in NH₃ oxidation
J. Pérez-Ramírez, N. López, E.V. Kondratenko
J. Phys. Chem. 2010, 114, 16660-16668 (doi:10.1021/jp106193w)
Molecular understanding of alkyne hydrogenation for the design of selective catalysts
B. Bridier, N. López, J. Pérez-Ramírez
Dalton Trans. 2010, 39, 8412-8419 (doi:10.1039/C0DT00010H)
Reactivity of Mg-Al hydrotalcites in solid and delaminated forms in ammonium carbonate solutions
G. Stoica, M. Santiago, S. Abelló, J. Pérez-Ramírez
Solid State Sci. 2010, 12, 1822-1830 (doi:10.1016/j.solidstatesciences.2010.08.003)
Properties and functions of hierarchical ferrierite zeolites obtained by sequential post-synthesis treatments
D. Verboekend, R. Caicedo-Realpe, A. Bonilla, M. Santiago, J. Pérez-Ramírez
Chem. Mater. 2010, 22, 4679-4689 (doi:10.1021/cm100886y)
Cooperative effects in ternary Cu-Ni-Fe catalysts lead to enhanced alkene selectivity in alkyne hydrogenation
B. Bridier, J. Pérez-Ramírez
J. Am. Chem. Soc. 2010, 132, 4321-4327 (doi:10.1021/ja9101997)
Acidity and accessibility studies on mesoporous ITQ-4 zeolite
D. Verboekend, L.A. Villaescusa, K. Thomas, I. Stan, J. Pérez-Ramírez
Catal. Today 2010, 152, 11-16 (doi:10.1016/j.cattod.2010.02.004)
Partial hydrogenation of propyne over copper-based catalysts and comparison with nickel-based analogues
B. Bridier, N. López, J. Pérez-Ramírez
J. Catal. 2010, 269, 80-92 (doi:10.1016/j.jcat.2009.10.019)
Mesoporous ZSM-5 zeolites prepared by a two-step route comprising sodium aluminate and acid treatments
R. Caicedo-Realpe, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2010, 128, 91-100 (doi:10.1016/j.micromeso.2009.08.009)
Hierarchical ZSM-5 zeolites in shape-selective xylene isomerization: role of mesoporosity and acid site speciation
C. Fernandez, I. Stan, J.-P. Gilson, K. Thomas, A. Vicente, A. Bonilla, J. Pérez-Ramírez
Chem. Eur. J. 2010, 16, 6224-6233 (doi:10.1002/chem.200903426)
Interplay of properties and functions upon introduction of mesoporosity in ITQ-4 zeolite
D. Verboekend, J.C. Groen, J. Pérez-Ramírez
Adv. Funct. Mater. 2010, 20, 1441-1450 (doi:10.1002/adfm.200902205)
DRIFTS study of the catalytic N₂O reduction by SO₂ on FeZSM-5
S. Abelló, M.A.G. Hevia, M. Santiago, J. Pérez-Ramírez
Catal. Commun. 2010, 11, 1058-1062 (doi:10.1016/j.catcom.2010.05.009)
Perturbing the properties of layered double hydroxides by continuous coprecipitation with short residence time
S. Abelló, S. Mitchell, M. Santiago, G. Stoica, J. Pérez-Ramírez
J. Mater. Chem. 2010, 20, 5878-5887 (doi:10.1039/C0JM00088D)
Interplay between carbon monoxide, hydrides, and carbides in selective alkyne hydrogenation on palladium
M. García-Mota, B. Bridier, N. López, J. Pérez-Ramírez
J. Catal. 2010, 273, 92-102 (doi:10.1016/j.jcat.2010.04.018)
Accelerated generation of intracrystalline mesoporosity in zeolites by microwave-mediated desilication
S. Abelló, J. Pérez-Ramírez
Phys. Chem. Chem. Phys. 2009, 11, 2959-2963 (doi:10.1039/b819543a)
Tailored mesoporosity development in zeolite crystals by partial detemplation and desilication
J. Pérez-Ramírez, S. Abelló, A. Bonilla, J.C. Groen
Adv. Funct. Mater. 2009, 19, 164-172 (doi:10.1002/adfm.200800871, front-cover)
Theoretical investigation of the inversion parameter in Co_3-sAl_sO₄ (s = 0-3) spinel structures
F. Tielens, M. Calatayud, R. Franco, J.M. Recio, J. Pérez-Ramírez, C. Minot
Solid State Ionics 2009, 180, 1011-1016 (doi:10.1016/j.ssi.2009.03.023)
Mechanism of ammonia oxidation over PGM (Pt, Pd, Rh) wires by temporal analysis of products and density functional theory
J. Pérez-Ramírez, E.V. Kondratenko, G. Novell-Leruth, J.M. Ricart
J. Catal. 2009, 261, 217-223 (doi:10.1016/j.jcat.2008.11.018)
Mesoporous metallosilicate zeolites by desilication: On the generic pore-inducing role of framework trivalent heteroatoms
J.C. Groen, R. Caicedo-Realpe, S. Abelló, J. Pérez-Ramírez
Mater. Lett. 2009, 63, 1037-1040 (doi:10.1016/j.matlet.2009.02.001)
Synthesis of dimethyl carbonate by transesterification of ethylene carbonate over activated dawsonites
G.Stoica, S. Abelló, J. Pérez-Ramírez
ChemSusChem 2009, 2, 301-304 (doi:10.1002/cssc.200800195)
Quantification of enhanced acid site accessibility in hierarchical zeolites - The accessibility index
F. Thibault-Starzyk, I. Stan, S. Abelló, A. Bonilla, K. Thomas, C. Fernandez, J.-P. Gilson, J. Pérez-Ramírez
J. Catal. 2009, 264, 11-14 (doi:10.1016/j.jcat.2009.03.006)
Evaluation of catalysts for N₂O abatement in fluidized-bed combustion
M. Santiago, M.A.G. Hevia, J. Pérez-Ramírez
Appl. Catal. B 2009, 90, 83-88 (doi:10.1016/j.apcatb.2009.02.017)
Desilication of ferrierite zeolite for porosity generation and improved effectiveness in polyethylene pyrolysis
A. Bonilla, D. Baudouin, J. Pérez-Ramírez
J. Catal. 2009, 265, 170-180 (doi:10.1016/j.jcat.2009.04.022)
Mesoporous ZSM-5 zeolite catalysts prepared by desilication with organic hydroxides and comparison with NaOH leaching
S. Abelló, A. Bonilla, J. Pérez-Ramírez
Appl. Catal. A 2009, 364, 191-198 (doi:10.1016/j.apcata.2009.05.055)
Na-dawsonite derived aluminates for DMC production by transesterification of ethylene carbonate
G. Stoica, S. Abelló, J. Pérez-Ramírez
Appl. Catal. A 2009, 365, 252-260 (doi:10.1016/j.apcata.2009.06.022)
Epoxidation catalysts derived from aluminium and gallium dawsonites
G. Stoica, M. Santiago, P.A. Jacobs, J. Pérez-Ramírez, P.P. Pescarmona
Appl. Catal. A 2009, 371, 43-53 (doi:10.1016/j.apcata.2009.09.021)
Zeolite catalysts with tunable hierarchy factor by pore-growth moderators
J. Pérez-Ramírez, D. Verboekend, A. Bonilla, S. Abelló
Adv. Funct. Mater. 2009, 19, 3972-3979 (doi:10.1002/adfm.200901394, front-cover)
Assessment of the low-temperature EnviNOx^®variant for catalytic N₂O abatement over steam-activated FeZSM-5
M.A.G. Hevia, J. Pérez-Ramírez
Appl. Catal. B 2008, 77, 248-254 (doi:10.1016/j.apcatb.2007.07.013)
Hierarchical zeolites: enhanced utilisation of microporous crystals in catalysis by advances in materials design
J. Pérez-Ramírez, C.H. Christensen, K. Egeblad, C.H. Christensen, J.C. Groen
Chem. Soc. Rev. 2008, 37, 2530-2542 (doi:10.1039/B809030K)
Mechanism of HCl oxidation (Deacon reaction) over RuO₂
N. López, J. Gómez-Segura, R.P. Marín, J. Pérez-Ramírez
J. Catal. 2008, 255, 29-39 (doi:10.1016/j.jcat.2008.01.020)
Visualizing the crystal structure and locating the catalytic activity of micro- and mesoporous ZSM-5 zeolite crystals using in situ optical and fluorescence microscopy
M.H.F. Kox, E. Stavitski, J.C. Groen, J. Pérez-Ramírez, F. Kapteijn, B.M. Weckhuysen
Chem. Eur. J. 2008, 14, 1718-1725 (doi:10.1002/chem.200701591)
The role of Brønsted acidity in the SCR of NO over Fe-MFI catalysts
M. Schwidder, M. Santosh Kumar, U. Bentrup, J. Pérez-Ramírez, A. Brückner, W. Grünert
Microporous Mesoporous Mater. 2008, 111, 124-133 (doi:10.1016/j.micromeso.2007.07.019)
Stability, reutilization, and scalability of activated hydrotalcites in aldol condensation
S. Abelló, D. Vijaya-Shankar, J. Pérez-Ramírez
Appl. Catal. A 2008, 342, 119-125 (doi:10.1016/j.apcata.2008.03.010)
Carbon-templated hexaaluminates with enhanced surface area and catalytic performance
M. Santiago, J.C. Groen, J. Pérez-Ramírez
J. Catal. 2008, 257, 152-162 (doi:10.1016/j.jcat.2008.04.017)
Mesoporous beta zeolite obtained by desilication
J.C. Groen, S. Abelló, L.A. Villaescusa, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2008, 114, 93-102 (doi:10.1016/j.micromeso.2007.12.025)
Selective homogeneous and heterogeneous gold catalysis with alkynes and alkenes: similar behavior, different origin
M. García-Mota, N. Cabello, F. Maseras, A.M. Echavarren, J. Pérez-Ramírez, N. López
ChemPhysChem 2008, 9, 1624-1629 (doi:10.1002/cphc.200800246)
Reconstruction of dawsonite by alumina carbonation in (NH₄)₂CO₃: requisites and mechanism
G. Stoica, J.C. Groen, S. Abelló, R. Manchanda, J. Pérez-Ramírez
Chem. Mater. 2008, 20, 3973-3982 (doi:10.1021/cm800359t)
Discriminating reasons for selectivity enhancement of CO in alkyne hydrogenation on palladium
N. López, B. Bridier, J. Pérez-Ramírez
J. Phys. Chem. C 2008, 112, 9346-9350 (doi:10.1021/jp711258q)
Pt(100)-catalyzed ammonia oxidation studied by DFT: mechanism and microkinetics
G. Novell-Leruth, J.M. Ricart, J. Pérez-Ramírez
J. Phys. Chem. C 2008, 112, 13554-13562 (doi:10.1021/jp802489y)
Mechanistic origin of the different activity of Rh-ZSM-5 and Fe-ZSM-5 in direct N₂O decomposition
E.V. Kondratenko, V.A. Kondratenko, M. Santiago, J. Pérez-Ramírez
J. Catal. 2008, 256, 248-258 (doi:10.1016/j.jcat.2008.03.016)
Activated takovite catalysts for partial hydrogenation of ethyne, propyne, and propadiene
S. Abelló, D. Verboekend, B. Bridier, J. Pérez-Ramírez
J. Catal. 2008, 259, 85-95 (doi:10.1016/j.jcat.2008.07.012)
Toward functional clathrasils: size- and composition-controlled octadecasil nanocrystals by desilication
J. Pérez-Ramírez, S. Abelló, L.A. Villaescusa, A. Bonilla
Angew. Chem. Int. Ed. 2008, 47, 7913-7917 (doi:10.1002/anie.200802393, VIP, front-cover)
Angew. Chem. 2008, 120, 8031-8035 (doi:10.1002/ange.200802393, VIP, front-cover)
Reply to ‘‘Comments on ‘Assessment of the low-temperature EnviNOx^®variant for catalytic N₂O abatement over steam-activated FeZSM-5: Miguel A.G. Hevia, Javier Pérez-Ramírez, Appl. Catal. B: Environ. 77 (2008) 248–254”
M.A.G. Hevia, J. Pérez-Ramírez
Appl. Catal. B 2008, 84, 543-544 (doi:10.1016/j.apcatb.2008.05.006)
Optimal hydrocarbon selection for catalytic N₂O reduction over iron-containing ZSM-5 zeolite
M.A.G. Hevia, J. Pérez-Ramírez
Environ. Sci. Technol. 2008, 42, 8896-8900 (doi:10.1021/es801971w)
SO₂-promoted catalytic N₂O removal over iron zeolites
J. Pérez-Ramírez, M.A.G. Hevia, S. Abelló
Chem. Commun. 2008, 5351-5353 (doi:10.1039/b811703a)
Prospects of N₂O emission regulations in the European fertilizer industry
J. Pérez-Ramírez
Appl. Catal., B 2007, 70, 31-35 (doi:10.1016/j.apcatb.2005.11.019)
Reforming dawsonite by memory effect of AACH-derived aluminas
G. Stoica, J. Pérez-Ramírez
Chem. Mater. 2007, 19, 4783-4790 (doi:10.1021/cm071351g)
Ammonia dissociation on Pt(100), Pt(111) and Pt(211): a comparative density functional theory study
W.K. Offermans, A.P.J. Jansen, R.A. van Santen, G. Novell-Leruth, J.M. Ricart, J. Pérez-Ramírez
J. Phys. Chem. C 2007, 111, 17551-17557 (doi:10.1021/jp073083f)
Catalytic reduction of N₂O over Fe-ZSM-5 zeolite. Comparison of CH₄, CO, and their mixtures in the absence or presence of excess O₂
M.N. Debbagh, C. Salinas Martínez de Lecea, J. Pérez-Ramírez
Appl. Catal., B 2007, 70, 335-341 (doi:10.1016/j.apcatb.2005.11.028)
Aldol condensation of campholenic aldehyde and MEK over activated hydrotalcite
S. Abelló, F. Medina, D. Tichit, J. Pérez-Ramírez, Y. Cesteros, P. Salagre, J.E. Sueiras
Appl. Catal., B 2007, 70, 577-584 (doi:10.1016/j.apcatb.2006.01.021)
Evolution, achievements, and perspectives of the TAP technique
J. Pérez-Ramírez, E.V. Kondratenko
Catal. Today 2007, 121, 160-169 (doi:10.1016/j.cattod.2007.01.001)
Mechanistic peculiarities of N₂O reduction by CH₄ over Fe-silicalite
E.V. Kondratenko, J. Pérez-Ramírez
Catal. Today 2007, 119, 243-246 (doi:10.1016/j.cattod.2006.08.007)
Rational modelling of the CPO of methane over platinum gauze. Elementary gas-phase and surface mechanisms coupled with flow simulations
R. Quiceno, O. Deutschmann, J. Warnatz, J. Pérez-Ramírez
Catal. Today 2007, 119, 311-316 (doi:10.1016/j.cattod.2006.08.045)
Ammonia dehydrogenation over platinum-group metal surfaces. Structure, stability and reactivity of adsorbed NH_x species
G. Novell-Leruth, A. Valcárcel, J. Pérez-Ramírez, J.M. Ricart
J. Phys. Chem. C 2007, 111, 860-868 (doi:10.1021/jp064742b)
Memory effect of activated Mg-Al hydrotalcite. In situ XRD studies during decomposition and gas-phase reconstruction
J. Pérez-Ramírez, S. Abelló, N.M. van der Pers
Chem. Eur. J. 2007, 13, 870-878 (doi:10.1002/chem.200600767)
Direct demonstration of enhanced diffusion in mesoporous ZSM-5 zeolite obtained via controlled desilication
J.C. Groen, W. Zhu, S. Brouwer, S. Huynink, F. Kapteijn, J.A. Moulijn, J. Pérez-Ramírez
J. Am. Chem. Soc. 2007, 129, 355-360 (doi:10.1021/ja065737o)
Metal-substituted hexaaluminates for high-temperature N₂O abatement
J. Pérez-Ramírez, M. Santiago
Chem. Commun. 2007, 619-621 (doi:10.1039/B613602H)
In situ studies during thermal activation of dawsonite-type compounds to oxide catalysts
M.S. Yalfani, M. Santiago, J. Pérez-Ramírez
J. Mater. Chem. 2007, 17, 1222-1229 (doi:10.1039/B615264C)
Influence of the divalent cation on the thermal activation and reconstruction of hydrotalcite-like compounds
J. Pérez-Ramírez, S. Abelló, N.M. van der Pers
J. Phys. Chem. C 2007, 111, 3642-3650 (doi:10.1021/jp064972q)
Decomposition of N₂O over hexaaluminate catalysts
M. Santiago, J. Pérez-Ramírez
Environ. Sci. Technol. 2007, 41, 1704-1709 (doi:10.1021/es061894b)
Micro-kinetic analysis of direct N₂O decomposition over steam-activated Fe-silicalite from transient experiments in the TAP reactor
E.V. Kondratenko, J. Pérez-Ramírez
Catal. Today 2007, 247, 383-386 (doi:10.1016/j.cattod.2006.08.066)
Origin of the superior hydrogenation selectivity of gold nanoparticles in alkyne+alkene mixtures: triple vs double bond activation
Y. Segura, N. López, J. Pérez-Ramírez
J. Catal. 2007, 247, 383-386 (doi:10.1016/j.jcat.2007.02.019)
Hydrogenolysis of methylcyclopentane over bimetallic Ir-Au/gamma-Al₂O₃ catalysts
R.J. Chimentão, G.P. Valença, F. Medina, J. Pérez-Ramírez
Appl. Surf. Sci. 2007, 253, 5888-5893 (doi:10.1016/j.apsusc.2006.12.061)
Accelerated study of the citral-acetone condensation kinetics over activated Mg-Al hydrotalcite
S. Abelló, S. Dhir, G. Colet, J. Pérez-Ramírez
Appl. Catal., A 2007, 325, 121-129 (doi:10.1016/j.apcata.2007.03.022)
Alkaline post-treatment of MFI zeolites. From accelerated screening to scale-up
J.C. Groen, J.A. Moulijn, J. Pérez-Ramírez
Ind. Eng. Chem. Res. 2007, 46, 4193-4201 (doi:10.1021/ie061146v)
Deactivation and regeneration of iron-containing MFI zeolites in propane oxidative dehydrogenation by N₂O
O. Sánchez-Galofré, Y. Segura, J. Pérez-Ramírez
J. Catal. 2007, 249, 123-133 (doi:10.1016/j.jcat.2007.04.010)
Kinetics of the N₂O+CO reaction over steam-activated FeZSM-5
M.N. Debbagh, A. Bueno-López, C. Salinas-Martínez de Lecea, J. Pérez-Ramírez
Appl. Catal., A 2007, 327, 66-72 (doi:10.1016/j.apcata.2007.04.029)
Mechanism of ammonia oxidation over oxides studied by temporal analysis of products
J. Pérez-Ramírez, E.V. Kondratenko
J. Catal. 2007, 250, 240-246 (doi:10.1016/j.jcat.2007.06.014)
Alkaline-mediated mesoporous mordenite zeolites for acid-catalyzed conversions
J.C. Groen, T. Sano, J.A. Moulijn, J. Pérez-Ramírez
J. Catal. 2007, 251, 21-27 (doi:10.1016/j.jcat.2007.07.020)
In situ monitoring of desilication of MFI-type zeolites in alkaline medium
J.C. Groen, G.M. Hamminga, J.A. Moulijn, J. Pérez-Ramírez
Phys. Chem. Chem. Phys. 2007, 9, 4822-4830 (doi:10.1039/b705418a)
Evidence of the vital role of the pore network on various catalytic conversion of N₂O over Fe-silicalite and Fe-SBA-15 with the same iron constitution
M. Santosh Kumar, J. Pérez-Ramírez, M.N. Debbagh, B. Smarsly, A. Brückner
Appl. Catal., B 2006, 62, 244-254 (doi:10.1016/j.apcatb.2005.07.012)
Distinct time-on-stream behavior of pure Pt and Rh metals and Pt-Rh alloys in direct N₂O decomposition at high temperatures
E.V. Kondratenko, R. Kraehnert, M. Rodnick, M. Baerns, J. Pérez-Ramírez
Appl. Catal., A 2006, 298, 73-79 (doi:10.1016/j.apcata.2005.09.022)
A periodic DFT study of the structural and electronic properties of bulk CoAl₂O₄ spinel
F. Tielens, M. Calatayud, R. Franco, J.M. Recio, J. Pérez-Ramírez, C. Minot
J. Phys. Chem. B 2006, 110, 988-995 (doi:10.1021/jp053375l)
Importance of the influence of oxygen species generated by N₂O decomposition for hydrocarbon activation over Fe-silicalite
E.V. Kondratenko, J. Pérez-Ramírez
Appl. Catal., B 2006, 64, 35-41 (doi:10.1016/j.apcatb.2005.10.019)
Modelling of the high-temperature catalytic partial oxidation of methane over platinum gauze. Detailed gas-phase and surface chemistries coupled with 3D flow field simulations
R. Quiceno, O. Deutschmann, J. Warnatz, J. Pérez-Ramírez
Appl. Catal., A 2006, 303, 166-176 (doi:10.1016/j.apcata.2006.01.041)
Thermal decomposition of hydrotalcite-like compounds studied by a Tapered Element Oscillating Microbalance (TEOM). Comparison with TGA and DTA
J. Pérez-Ramírez, S. Abelló
Thermochim. Acta 2006, 444, 47-82 (doi:10.1016/j.tca.2006.02.031)
Activity of commercial zeolites with iron impurities in direct N₂O decomposition
A.H. Øygarden, J. Pérez-Ramírez
Appl. Catal., B 2006, 65, 163-167 (doi:10.1016/j.apcatb.2006.03.002)
In-line dispersion-precipitation method for the synthesis of metal-substituted dawsonites. Genesis of oxide materials with superior properties
M. Santiago, M.S. Yalfani, J. Pérez-Ramírez
J. Mater. Chem. 2006, 16, 2886-2889 (doi:10.1039/B607031K)
Application of mercury intrusion porosimetry for characterization of combined micro- and mesoporous zeolites
J.C. Groen, S. Brouwer, L.A.A. Peffer, J. Pérez-Ramírez
Part. Part. Syst. Charact. 2006, 23, 101-106 (doi:10.1002/ppsc.200601010)
Iron site modification upon alkaline-treatment of Fe-ZSM-5 zeolites. Opportunities for improved N₂O decomposition activity
J.C. Groen, A. Brückner, E. Berrier, L. Maldonado, J.A. Moulijn, J. Pérez-Ramírez
J. Catal. 2006, 243, 212-216 (doi:10.1016/j.jcat.2006.07.001)
Tuning nanomaterials’ characteristics by a miniaturized in line dispersion-precipitation method: application to hydrotalcite synthesis
S. Abelló, J. Pérez-Ramírez
Adv. Mater. 2006, 18, 2436-2439 (doi:10.1002/adma.200600673)
Alkaline treatment of iron-containing MFI zeolites. Influence on mesoporosity development and iron speciation
J.C. Groen, L. Maldonado, E. Berrier, A. Brückner, J.A. Moulijn, J. Pérez-Ramírez
J. Phys. Chem. B 2006, 110, 20369-20378 (doi:10.1021/jp0643193)
Mechanism and kinetics of direct N₂O decomposition over Fe-MFI zeolites with different iron speciation from Temporal Analysis of Products
E.V. Kondratenko, J. Pérez-Ramírez
J. Phys. Chem. B 2006, 110, 22586-22595 (doi:10.1021/jp063492w)
Steam activation of Mg-Al hydrotalcite. Influence on the properties of the derived mixed oxides
S. Abelló, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2006, 96, 102-108 (doi:10.1016/j.micromeso.2006.06.018)
Desilication: on the controlled generation of mesoporosity in MFI zeolites
J.C. Groen, J.A. Moulijn, J. Pérez-Ramírez
J. Mater. Chem. 2006, 16, 2121-2131 (doi:10.1039/b517510k, front cover)
Impact of the preparation method and iron impurities in Fe-ZSM-5 zeolites for propylene production via propane oxidative dehydrogenation with N₂O
J. Pérez-Ramírez, A. Gallardo-Llamas
Appl. Catal., A 2005, 279, 117-123 (doi:10.1016/j.apcata.2004.10.020)
Aldol condensations over reconstructed Mg-Al hydrotalcites. Structure-activity relationships related to the rehydratation method
S. Abelló, F. Medina, D. Tichit, J. Pérez-Ramírez, J.C. Groen, J.E. Suerias, P. Salagre, Y. Cesteros
Chem. Eur. J. 2005, 11, 728-739 (doi:10.1002/chem.200400409)
Perovskite membranes in ammonia oxidation. Towards process intensification in nitric acid manufacture
J. Pérez-Ramírez, B. Vigeland
Angew. Chem., Int. Ed. 2005, 44, 1112-1115 (doi:10.1002/anie.200462024)
Angew. Chem. 2005, 117, 1136-1139 (doi:10.1002/ange.200462024)
Cyclic process for propylene production via oxidative dehydrogenation of propane with N₂O over FeZSM-5
A. Gallardo-Llamas, C. Mirodatos, J. Pérez-Ramírez
Ind. Eng. Chem. Res. 2005, 44, 455-462 (doi:10.1021/ie0493863)
Selectivity-directing factors of ammonia oxidation over PGM gauzes in the Temporal Analysis of Products reactor: Secondary interactions of NH₃ and NO
J. Pérez-Ramírez, E.V. Kondratenko, V.A. Kondratenko, M. Baerns
J. Catal. 2005, 229, 303-313 (doi:10.1016/j.jcat.2004.09.020)
Study of alkaline-doping agents on the performance of reconstructed Mg-Al hydrotalcites in aldol condensations
S. Abelló, F. Medina, D. Tichit, J. Pérez-Ramírez, X. Rodríguez, J.E. Suerias, P. Salagre, Y. Cesteros
Appl. Catal., A 2005, 281, 191-198 (doi:10.1016/j.apcata.2004.11.037)
Nanoplatelet-based reconstructed hydrotalcites: towards more efficient solid base catalysts in aldol condensations
S. Abelló, F. Medina, D. Tichit, J. Pérez-Ramírez, Y. Cesteros, P. Salagre, J.E. Sueiras
Chem. Commun. 2005, 1453-1455 (doi:10.1039/B417322H)
Structure and catalytic processes of N-containing species on Rh(111) from first principles
J.M. Ricart, F. Ample, A. Clotet, J.W. Niemantsverdriet, J.-F. Paul, J. Pérez-Ramírez
J. Catal. 2005, 232, 179-185 (doi:10.1016/j.jcat.2005.03.010)
Evolution of isomorphously substituted iron zeolites during activation: Fe-beta vs Fe-ZSM-5
J. Pérez-Ramírez, J.C. Groen, A. Brückner, M.S. Kumar, N.M. Debbagh, U. Bentrup, L.A. Villaescusa
J. Catal. 2005, 232, 318-334 (doi:10.1016/j.jcat.2005.03.018)
Transient studies on the mechanism of N₂O activation and reaction with CO and C₃H₈ over Fe-silicalite
J. Pérez-Ramírez, E.V. Kondratenko, N.M. Debbagh
J. Catal. 2005, 233, 442-452 (doi:10.1016/j.jcat.2005.05.014)
Mechanism of hierarchical porosity development in MFI zeolites by desilication: The role of aluminium as a pore-directing agent
J.C. Groen, L.A.A. Peffer, J.A. Moulijn, J. Pérez-Ramírez
Chem. Eur. J. 2005, 11, 4983-4994 (doi:10.1002/chem.200500045)
Transient studies on the effect of oxygen on the high-temperature NO reduction by NH₃ over Pt-Rh gauze
E.V. Kondratenko, J. Pérez-Ramírez
Appl. Catal., A 2005, 289, 97-103 (doi:10.1016/j.apcata.2005.04.017)
Lanthanum ferrite-based membranes in ammonia oxidation. Opportunities for ‘pocket-sized’ nitric acid plants
J. Pérez-Ramírez, B. Vigeland
Catal. Today 2005, 105, 436-442 (doi:10.1016/j.cattod.2005.06.057)
Creation of hollow zeolite architectures by controlled desilication of Al-zoned ZSM-5 crystals
J.C. Groen, T. Bach, U. Ziese, A.M. Paulaime-van Donk, K.P. de Jong, J.A. Moulijn, J. Pérez-Ramírez
J. Am. Chem. Soc. 2005, 127, 10792-10793 (doi:10.1021/ja052592x)
DFT characterization of adsorbed NH_x species on Pt(100) and Pt(111) surfaces
G. Novell-Leruth, A. Valcárcel, A. Clotet, J.M. Ricart, J. Pérez-Ramírez
J. Phys. Chem. B 2005, 109, 18061-18069 (doi:10.1021/jp051682l)
Framework composition effects on the performance of steam-activated Fe-MFI zeolites for propane oxidation to propylene with N₂O
J. Pérez-Ramírez, A. Gallardo-Llamas
J. Phys. Chem. B 2005, 109, 20529-20538 (doi:10.1021/jp054447b)
Highly efficient Fe-silicalite zeolite in direct propane ammoxidation with N₂O and O₂
J. Pérez-Ramírez, N. Blangenois, P. Ruiz
Catal. Lett. 2005, 104, 163-167 (doi:10.1007/s10562-005-7946-8)
Decoupling mesoporosity formation and acidity modification in ZSM-5 zeolites by sequential desilication-dealumination
J.C. Groen, J.A. Moulijn, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2005, 87, 153-161 (doi:10.1016/j.micromeso.2005.07.050)
Effect of NO on the SCR of N₂O with propane over Fe-zeolites
J. Pérez-Ramírez, F. Kapteijn
Appl. Catal., B 2004, 47, 177-187 (doi:10.1016/j.apcatb.2003.09.002)
Evidences of the origin of N₂O in the high-temperature NH₃ oxidation over Pt-Rh gauze
J. Pérez-Ramírez, E.V. Kondratenko
Chem. Commun. 2004, 376-377 (doi:10.1039/B312685D)
N₂O decomposition over liquid ion-exchanged Fe-BEA catalysts. Correlation between activity and the IR intensity of adsorbed NO at 1874 cm^-1
G. Mul, M.W. Zandbergen, F. Kapteijn, J.A. Moulijn, J. Pérez-Ramírez
Catal. Lett. 2004, 93, 113-120 (doi:10.1023/B:CATL.0000016958.22246.83)
On the introduction of intracrystalline mesoporosity in zeolites upon desilication in alkaline medium
J.C. Groen, L.A.A. Peffer, J.A. Moulijn, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2004, 69, 29-24 (doi:10.1016/j.micromeso.2004.01.002)
Reduction of N₂O with CO over FeMFI zeolites. Influence of the preparation method on the iron species and catalytic behaviour
J. Pérez-Ramírez, M. Santosh Kumar, A. Brückner
J. Catal. 2004, 223, 13-27 (doi:10.1016/j.jcat.2004.01.007)
N₂O-mediated propane oxidative dehydrogenation over steam-activated iron zeolites
J. Pérez-Ramírez, A. Gallardo-Llamas
J. Catal. 2004, 223, 382-388 (doi:10.1016/j.jcat.2004.02.005)
Oxidative functionalization of propane over FeMFI zeolites. Effect of reaction variables and catalyst constitution on the performance
E.V. Kondratenko, J. Pérez-Ramírez
Appl. Catal., A 2004, 267, 181-189 (doi:10.1016/j.apcata.2004.03.003)
Critical appraisal of mesopore characterization by adsorption analysis
J.C. Groen, J. Pérez-Ramírez
Appl. Catal., A 2004, 268, 120-124 (doi:10.1016/j.apcata.2004.03.031)
Mechanism and kinetics of the selective NO reduction over Co-ZSM-5 studied by the SSITKA technique. Part 2: Reactivity of adsorbed NO_x species with methane
E.M. Sadovskaya, A.P. Suknev, L.G. Pinaeva, V.B. Goncharov, B.S. Bal’zhinimaev, C. Chupin, J. Pérez-Ramírez, C. Mirodatos
J. Catal. 2004, 225, 179-189 (doi:10.1016/j.jcat.2004.03.032)
Selectivity-directing factors of ammonia oxidation over PGM gauzes in the Temporal Analysis of Products reactor: Primary interactions of NH₃ and O₂
J. Pérez-Ramírez, E.V. Kondratenko, V.A. Kondratenko, M. Baerns
J. Catal. 2004, 227, 90-100 (doi:10.1016/j.jcat.2004.06.023)
Mesoporosity development in ZSM-5 zeolite upon optimized desilication conditions in alkaline medium
J.C. Groen, L.A.A. Peffer, J.A. Moulijn, J. Pérez-Ramírez
Colloid Surface A 2004, 241, 53-58 (doi:10.1016/j.colsurfa.2004.04.012)
Optimal aluminium-assisted mesoporosity development in MFI zeolites by desilication
J.C. Groen, J.C. Jansen, J.A. Moulijn, J. Pérez-Ramírez
J. Phys. Chem. B 2004, 208, 13062-13065 (doi:10.1021/jp047194f)
Catalytic conversion of N₂O over FeZSM-5 zeolite in the presence of CO and NO
M.N. Debbagh Boutarbouch, J.M. García Cortés, M. Soussi El Begrani, C. Salinas Martínez de Lecea, J. Pérez-Ramírez
Appl. Catal., B 2004, 54, 115-123 (doi:10.1016/j.apcatb.2004.06.013)
Active iron sites associated with the reaction mechanism of N₂O conversions over steam-activated FeMFI zeolites
J. Pérez-Ramírez
J. Catal. 2004, 227, 512-522 (doi:10.1016/j.jcat.2004.08.005)
N₂O-mediated propane oxidative dehydrogenation over Fe-zeolites. TEOM studies for continuous propylene production in a cyclically-operated reactor
J. Pérez-Ramírez, A. Gallardo-Llamas, C. Daniel, C. Mirodatos
Chem. Eng. Sci. 2004, 59, 5535-5543 (doi:10.1016/j.ces.2004.07.035)
Theoretical studies of N₂O adsorption and reactivity to N₂ and NO on Rh(111)
J.-F. Paul, J. Pérez-Ramírez, F. Ample, J.M. Ricart
J. Phys. Chem. B 2004, 108, 17921-17927 (doi:10.1021/jp048138h)
Steam-activated FeMFI zeolites. Evolution of iron species and activity in direct N₂O decomposition
J. Pérez-Ramírez, F. Kapteijn, J.C. Groen, A. Doménech, G. Mul, J.A. Moulijn
J. Catal. 2003, 218, 234-238 (doi:10.1016/S0021-9517(02)00021-0)
Structural and activity changes in Pt-beta catalysts during deNO_x HC-SCR
J.M. García-Cortés, J. Pérez-Ramírez, M.J. Illán-Gómez, C. Salinas-Martínez de Lecea
Catal. Commun. 2003, 4, 165-170 (doi:10.1016/S0021-9517(03)00088-5)
Active site structure sensitivity in N₂O conversion over FeMFI zeolites
J. Pérez-Ramírez, F. Kapteijn, A. Brückner
J. Catal. 2003, 218, 234-238 (doi:10.1016/S0021-9517(03)00087-3)
On the activation of Pt/Al₂O₃ catalysts in lean deNO_x by sintering: Titration of active sites using Multitrack
A.R. Vaccaro, G. Mul, J. Pérez-Ramírez, J.A. Moulijn
Appl. Catal., B 2003, 46, 687-702 (doi:10.1016/S0926-3373(03)00271-6)
On the structure sensitivity of the SCR of NO_x with hydrocarbons over Pt-beta catalysts
J.M. García-Cortés, J. Pérez-Ramírez, A.R. Vaccaro, J.N. Rozaud, M.J. Illán-Gómez, C. Salinas-Martínez de Lecea
J. Catal. 2003, 218, 111-122 (doi:10.1016/S0021-9517(03)00088-5)
Elucidation of the surprising role of NO on N₂O conversions over FeMFI zeolites
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
Kinet. Catal. 2003, 44, 639-647 (doi:10.1023/A:1026189905517)
Effect of NO on the catalytic removal of N₂O over FeZSM-5. Friend of foe
J. Pérez-Ramírez, F. Kapteijn
Catal. Commun. 2003, 4, 333-338 (doi:10.1016/S1566-7367(03)00083-9)
Transient study during direct N₂O decomposition over Pt-Rh gauze catalyst. Mechanistic and kinetic aspects of oxygen formation
E.V. Kondratenko, J. Pérez-Ramírez
Catal. Lett. 2003, 91, 211-216 (doi:10.1023/B:CATL.0000007157.87417.fe)
Steam-activated FeMFI zeolites as highly efficient catalysts for propane and N₂O valorisation via oxidative conversions
J. Pérez-Ramírez, E.V. Kondratenko
Chem. Commun. 2003, 2152-2153 (doi:10.1039/B305568J)
Pore size determination in modified micro- and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis
J.C. Groen, L.A.A. Peffer, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2003, 60, 1-17 (doi:10.1016/S1387-1811(03)00339-1)
High-throughput experimentation in catalyst testing and in kinetic studies for heterogeneous catalysis
J.A. Moulijn, J. Pérez-Ramírez, R.J. Berger, G. Hamminga, G. Mul, F. Kapteijn
Catal. Today 2003, 81, 457-471 (doi:10.1016/S0920-5861(03)00145-7)
Formation and control of N₂O in nitric acid production. Where do we stand today?
J. Pérez-Ramírez, F. Kapteijn, K. Schöffel, J.A. Moulijn
Appl. Catal., B 2003, 44, 117-183 (doi:10.1016/S0926-3373(03)00026-2)
Catalyst performance testing: The influence of bed dilution on the conversion observed
R.J. Berger, J. Pérez-Ramírez, F. Kapteijn, J.A. Moulijn
Chem. Eng. Sci. 2002, 90, 173-183 (doi:10.1016/S1385-8947(02)00078-5)
Ex-framework FeZSM-5 for control of N₂O in simulated tail-gases
J. Pérez-Ramírez, G. Mul, F. Kapteijn, X. Xu, J.A. Moulijn
Catal. Today 2002, 76, 55-74 (doi:10.1016/S0920-5861(02)00208-0)
Catalyst performance testing. Bed dilution revisited
R.J. Berger, J. Pérez-Ramírez, F. Kapteijn, J.A. Moulijn
Chem. Eng. Sci. 2002, 57, 4921-4932 (doi:10.1016/S0009-2509(02)00273-7)
Magnetic properties of Co-Al, Ni-Al, and Mg-Al hydrotalcites and their thermally decomposed products
J. Pérez-Ramírez, A. Ribera, F. Kapteijn, E. Coronado, C.J. Gómez
J. Mater. Chem. 2002, 12, 2370-2375 (doi:10.1039/B110314H)
NO-assisted N₂O decomposition over Fe-based catalysts. Effects of feed composition and catalyst constitution
J. Pérez-Ramírez, F. Kapteijn, G. Mul, J.A. Moulijn
J. Catal. 2002, 208, 211-223 (doi:10.1006/jcat.2002.3559)
NO adsorption on [Fe]MFI catalysts. Novel IR bands and evaluation of assignments
G. Mul, J. Pérez-Ramírez, F. Kapteijn, J.A. Moulijn
Catal. Lett. 2002, 80, 129-138 (doi:10.1023/A:1015456308687)
Adsorption of N₂O over silicalite-1
J.C. Groen, J. Pérez-Ramírez, W. Zhu
J. Chem. Eng. Data 2002, 47, 587-589 (doi:10.1021/je015527l)
Characterization of iron species in ex-framework FeZSM-5 catalyst by electrochemical methods
A. Doménech, J. Pérez-Ramírez, A. Ribera, G. Mul, F. Kapteijn, J.A. Moulijn
Catal. Lett. 2002, 80, 129-138 (doi:10.1023/A:1014937424671)
Physico-chemical characterization of FeZSM-5 during activation
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn, A.R. Overweg, A. Ribera, I.W.C.E. Arends
J. Catal. 2002, 207, 113-126 (doi:10.1006/jcat.2002.3511)
Direct N₂O decomposition over ex-framework FeMFI catalysts. Role of extra-framework species
J. Pérez-Ramírez, F. Kapteijn, G. Mul, J.A. Moulijn
Catal. Commun. 2002, 3, 19-23 (doi:10.1016/S1566-7367(01)00072-3)
Highly active SO₂-resistant ex-framework FeZSM-5 for direct N₂O decomposition in tail-gases from combustion processes
J. Pérez-Ramírez, F. Kapteijn, G. Mul, J.A. Moulijn
Appl. Catal., B 2002, 35, 227-234 (doi:10.1016/S0926-3373(01)00259-4)
Electrochemical characterization of iron sites in ex-framework FeZSM-5
A. Doménech, J. Pérez-Ramírez, A. Ribera, G. Mul, F. Kapteijn, I.W.C.E. Arends
J. Electroanal. Chem. 2002, 519, 72-84 (doi:10.1016/S0022-0728(01)00724-0)
Catalyst performance testing. Radial and axial dispersion related to dilution in fixed-bed laboratory reactors
R.J. Berger, J. Pérez-Ramírez, F. Kapteijn, J.A. Moulijn
Appl. Catal., A 2002, 227, 323-335 (doi:10.1016/S0926-860X(01)00950-4)
Formation of uniform mesopores in ZSM-5 zeolite upon alkaline post-treatments?
J.C. Groen, J. Pérez-Ramírez, L.A.A. Peffer
Chem. Lett. 2002, 94-95 (doi:10.1246/cl.2002.94)
Comments on "Vanadium- and chromium-containing mesoporous MCM-41 molecular sieves with hierarchical structure"
J.C. Groen, L.A.A. Peffer, J. Pérez-Ramírez
Microporous Mesoporous Mater. 2002, 51, 75-78 (doi:10.1016/S1387-1811(01)00472-3)
A TEOM-MS study on the decomposition of N₂O over a hydrotalcite-derived multimetallic mixed oxide catalyst
M.C. Román-Martínez, F. Kapteijn, D. Cazorla-Amorós, J. Pérez-Ramírez, J.A. Moulijn
Appl. Catal., A 2002, 225, 87-100 (doi:10.1016/S0926-860X(01)00770-0)
Superior performance of the ex-framework FeZSM-5 in catalytic N₂O decomposition in tail-gases from nitric acid plants
J. Pérez-Ramírez, F. Kapteijn, G. Mul, J.A. Moulijn
Chem. Commun. 2001, 693-694 (doi:10.1039/B100953M)
In situ investigation during the thermal decomposition of Co-Al-HTlc in different atmospheres
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
J. Mater. Chem. 2001, 11, 821-830 (doi:10.1039/b009320n)
On the stability of the thermally decomposed Co-Al hydrotalcite against retrotopotactic transformation
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
Mater. Res. Bull. 2001, 36, 1767-1775 (doi:10.1016/S0025-5408(01)00657-2)
A spectroscopic study of the effect of the trivalent cation on the thermal decomposition behaviour Co-based hydrotalcites
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
J. Mater. Chem. 2001, 11, 2529-2536 (doi:10.1039/B104989P)
In situ Fourier Transform infrared and Raman spectroscopic study on the thermal decomposition of Co-Al and Ni-Al hydrotalcites
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
Vib. Spectrosc. 2001, 27, 75-88 (doi:10.1016/S0924-2031(01)00119-9)
Comparative study of Pt-based catalysts on different supports in the low-temperature de-NO_x SCR with propene
J.M. García-Cortés, J. Pérez-Ramírez, M.J. Illán-Gómez, F. Kapteijn, J.A. Moulijn, C. Salinas-Martínez de Lecea
Appl. Catal., B 2001, 30, 399-408 (doi:10.1016/S0926-3373(00)00255-1)
Characterization and performance of Pt-USY in the SCR of NO_x with hydrocarbons under lean-burn conditions
J. Pérez-Ramírez, J.M. García-Cortés, F. Kapteijn, G. Mul, J.A. Moulijn, C. Salinas-Martínez de Lecea
Appl. Catal., B 2001, 29, 285-298 (doi:10.1016/S0926-3373(00)00210-1)
NO-assisted N₂O decomposition over ex-framework FeZSM-5. Mechanistic considerations
G. Mul, J. Pérez-Ramírez, F. Kapteijn, J.A. Moulijn
Catal. Lett. 2001, 77, 7-13 (doi:10.1023/A:1012791129268)
Preparation, characterization and performance of FeZSM-5 for the selective oxidation of benzene to phenol with N₂O
A. Ribera, I.W.C.E. Arends, S. de Vries, J. Pérez-Ramírez, R.A. Sheldon
J. Catal. 2000, 195, 187-197 (doi:10.1006/jcat.2000.2994)
Comments on "Infrared emission spectroscopic studies of the thermal transformation of Mg-, Ni-, and Co-hydrotalcite catalysts"
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
Appl. Catal., A 2000, 204, 265-267 (doi:10.1016/S0926-860X(00)00696-7)
Dual-bed catalytic system for NO_x-N₂O removal: a practical application for lean-burn deNO_x HC-SCR
J. Pérez-Ramírez, J.M. García-Cortés, F. Kapteijn, M.J. Illán-Gómez, A. Ribera, C. Salinas-Martínez de Lecea, J.A. Moulijn
Appl. Catal., B 2000, 25, 191-203 (doi:10.1016/S0926-3373(99)00131-9)
Dual-bed catalytic system for the selective reduction of NO_x with propene
J. Pérez-Ramírez, A.R. Vaccaro, F. Kapteijn, J.A. Moulijn
Chem. Eng. Technol. 2000, 23, 721-725 (doi:10.1002/1521-4125(200008)23:8<721::AID-CEAT721>3.0.CO;2-0)
Highly active and stable Pt-USY in the low-temperature de-NO_x HC-SCR
J. Pérez-Ramírez, G. Mul, F. Kapteijn, J.A. Moulijn
React. Kinet. Catal. Lett. 2000, 71, 33-40 (doi:10.1023/A:1010365628369)
Reduction of NO by propene over Pt, Pd and Rh-based ZSM-5 under lean-burn conditions
J. Pérez-Ramírez, J.M. García-Cortés, M.J. Illán-Gómez, F. Kapteijn, J.A. Moulijn, C. Salinas-Martínez de Lecea
React. Kinet. Catal. Lett. 2000, 69, 385-392 (doi:10.1023/A:1005680707127)
Effect of the support in de-NO_x HC-SCR over transition metal catalysts
J.M. García-Cortés, J. Pérez-Ramírez, M.J. Ilán-Gómez, F. Kapteijn, J.A. Moulijn, C. Salinas-Martínez de Lecea
React. Kinet. Catal. Lett. 2000, 70, 199-206 (doi:10.1023/A:1010347726288)
The six-flow reactor technology. A review on fast catalyst screening and kinetic studies
J. Pérez-Ramírez, R.J. Berger, G. Mul, F. Kapteijn, J.A. Moulijn
Catal. Today 2000, 60, 93-109 (doi:10.1016/S0920-5861(00)00321-7)
Structural promotion and stabilizing effect of Mg in the catalytic decomposition of nitrous oxide over calcined hydrotalcite-like compounds
J. Pérez-Ramírez, J. Overeijnder, F. Kapteijn, J.A. Moulijn
Appl. Catal., B 1999, 23, 59-72 (doi:10.1016/S0926-3373(99)00066-1)
High activity and stability of the Rh-free Co-based ex-hydrotalcite containing Pd in the catalytic decomposition of N₂O
J. Pérez-Ramírez, F. Kapteijn, J.A. Moulijn
Catal. Lett. 1999, 60, 133-138 (doi:10.1023/A:1019011124950)